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Issue 10, 1973
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Low co-ordination numbers in lanthanide and actinide compounds. Part I. The preparation and characterization of tris{bis(trimethylsilyl)-amido}lanthanides

Abstract

The new three-co-ordinated lanthanide complexes [Ln{N(SiMe3)2}3], where Ln = La, Ce, Pr, Nd, Sm, Eu, Gd, Ho, Yb, and Lu, and [Y{N(Sime3)2}3], have been prepared and their 1H n.m.r. and electronic spectra are reported and discussed. The magnetic susceptibility of the Gd complex at 98 and 298 K is reported.

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Article type: Paper
DOI: 10.1039/DT9730001021
Citation: J. Chem. Soc., Dalton Trans., 1973, 1021-1023
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    Low co-ordination numbers in lanthanide and actinide compounds. Part I. The preparation and characterization of tris{bis(trimethylsilyl)-amido}lanthanides

    D. C. Bradley, J. S. Ghotra and F. A. Hart, J. Chem. Soc., Dalton Trans., 1973, 1021
    DOI: 10.1039/DT9730001021

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