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Issue 16, 1973
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Effect of 2-substitution on the rearrangement of 1-cyclopropylvinyl cations

Abstract

2-Substitution in 1-cyclopropylvinyl cations produces a steric effect on cation generation and solvent trapping, but an electronic charge-stabilizing effect on cyclopropyl-to-cyclobutyl rearrangement.

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Article type: Paper
DOI: 10.1039/C39730000589
Citation: J. Chem. Soc., Chem. Commun., 1973, 589-590
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    Effect of 2-substitution on the rearrangement of 1-cyclopropylvinyl cations

    D. R. Kelsey and R. G. Bergman, J. Chem. Soc., Chem. Commun., 1973, 589
    DOI: 10.1039/C39730000589

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