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Volume 67, 1971
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N.m.r. studies of some dimethylthallium compounds

Abstract

The proton n.m.r. spectra of (Me2TlX)2(X = OEt, OBu-t, OPh, SMe, SO2Me, C5H5 and CCPh) have been observed. The methyl doublet in the dimethylthallium ethoxide spectra shows an unusual variation with temperature: tentative explanations are discussed. The variation of 2J(H…Tl) with mol ratio in mixtures of trimethylthallium and trimethylamine shows that this coupling constant has the same sign in Me3Tl and Me3Tl.NMe3.

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Article type: Paper
DOI: 10.1039/TF9716700007
Citation: Trans. Faraday Soc., 1971,67, 7-11
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    N.m.r. studies of some dimethylthallium compounds

    A. G. Lee and G. M. Sheldrick, Trans. Faraday Soc., 1971, 67, 7
    DOI: 10.1039/TF9716700007

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