Issue 0, 1971
From the journal:

Journal of the Chemical Society C: Organic

Natural acetylenes. Part XXXIII. The biogenesis of the C9 diacetylenic triol from the fungus Clitocybe rhizophora velen

G. C. Barley,   A. C. Day,   U. Graf,   SirEwart R. H. Jones,   I. O'Neill,   R. Tachikawa,   V. Thaller  and  R. A. Vere Hodge  

Abstract

Labelled diethyl malonate, methyl oleate, methyl linoleate, and methyl crepenynate (CH3·[CH2]4·C[triple bond, length as m-dash]C·CH2·CH[double bond, length half m-dash]CH·[CH2]7·CO2Me) were all incorporated into the triol CH3·CH2·CH(OH)·[C[triple bond, length as m-dash]C]2·CH(OH)·CH2·OH by cultures of the fungus in the expected manner. Specifically labelled (14C and 3H) lachnophyllum ester (CH3·CH2·CH2·[C[triple bond, length as m-dash]C]2·CH[double bond, length half m-dash]CH·CO2Me) has been synthesised and also shown to be a precursor of the triol.

A new metabolite, CH3[graphic omitted]CH·[C[triple bond, length as m-dash]C]2·CH2·CH2·OH, has been isolated.

About
Cited by
Related
Download options Please wait...

Article information

DOI
https://doi.org/10.1039/J39710003308
Article type
Paper

J. Chem. Soc. C, 1971, 3308-3313

Permissions

Request permissions

Natural acetylenes. Part XXXIII. The biogenesis of the C9 diacetylenic triol from the fungus Clitocybe rhizophora velen

G. C. Barley, A. C. Day, U. Graf, E. R. H. Jones, I. O'Neill, R. Tachikawa, V. Thaller and R. A. V. Hodge, J. Chem. Soc. C, 1971, 3308 DOI: 10.1039/J39710003308

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements