Monothiothenoyltrifluoroacetone (ttas) forms two series of complexes with Group VIA zerovalent metal carbonyls in which the ligand acts as a monodentate sulphur donor or as a bidentate sulphur–oxygen donor, the two series being related by a simple carbonyl displacement.
G. H. Barnett and M. K. Cooper, J. Chem. Soc. D, 1971, 1082 DOI: 10.1039/C29710001082
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