Irradiation of metal ion absorption bands of Rh(NH3)5I2+ produces trans-Rh(NH3)4OH2I2+ with 90% efficiency, suggestive of a square-pyramidal geometry for the ligand-field excited state.
T. L. Kelly and J. F. Endicott, J. Chem. Soc. D, 1971, 1061 DOI: 10.1039/C29710001061
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