The photoadditions of 2,3-dimethylbut-2-ene to benzene and hexafluorobenzene proceed mainly by 1,4-‘ene-type’ addition, which is promoted by a proton donor, and substitutive addition respectively, in contrast with the behaviour of other mono-olefins.
D. Bryce-Smith, B. E. Foulger, A. Gilbert and P. J. Twitchett, J. Chem. Soc. D, 1971, 794 DOI: 10.1039/C29710000794
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