Two unambiguous methods have been developed for the introduction of the 3,3-dimethylallyl group ortho- to a phenolic hydroxy-group and both methods have been used to prepare dihydro-6-deoxyjacareubin.
H. D. Locksley, A. J. Quillinan and F. Scheinmann, J. Chem. Soc. D, 1969, 1505 DOI: 10.1039/C29690001505
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