Prediction of second virial coefficients of mixtures from the principle of corresponding states

Abstract

Values of the mixed virial coefficients B₁₂ are predicted for twenty-eight mixtures where experimental values have been reported. McGlashan and Potter's reduced equation of state is used to calculate corresponding states values, Hudson and McCoubrey's combining rules being used for the mixed critical temperatures. A comparison is made between the experimental and predicted values, using both the Hudson and McCoubrey combining rule and the geometric mean rule for the critical temperatures. In the first six mixtures examined, which are a particularly good test of the procedure (because of differences in ionization potential and size of the two components), agreement is often obtained within the experimental error. In the case of the other twenty-two mixtures, sixteen are better represented by the new procedure.