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Some derivatives of steroids having the 3-methoxy-2,5(10)-diene structure in ring-A reacted with chromium, molybdenum, or tungsten carbonyls, to give the metal tricarbonyl adducts of the ring-A-aromatic 3-deoxy-steroids. The adducts can be decomposed to give the parent compounds. Oestrone methyl ether gives crystalline chromium tricarbonyl and molybdenum tricarbonyl adducts.
A. J. Birch, P. E. Cross, D. T. Connor and G. S. R. S. Rao, J. Chem. Soc. C, 1966, 54 DOI: 10.1039/J39660000054
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