Issue 57, 2021
From the journal:

Chemical Communications

Hg3(Te3O8)(SO4): a new sulfate tellurite with a novel structure and large birefringence explored from d10 metal compounds†

Peng-Fei Li,ab   Chun-Li Hu,a   Ya-Ping Gong,a   Fang Kong ORCID logo *ac  and  Jiang-Gao Mao ORCID logo a  

* Corresponding authors

a State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, P. R. China
E-mail: kongfang@fjirsm.ac.cn

b College of Chemical Engineering, Fuzhou University, Fuzhou 350116, P. R. China

c University of Chinese Academy of Sciences, Beijing 100190, P. R. China

Abstract

Our exploration of novel inorganic solids with large birefringence in the d10 Metal–Te4+–SO42− system afforded four new sulfate tellurites, Ga2(TeO3)(SO4)(OH)2, In2(TeO3)2(SO4)(H2O), Zn4(Te3O7)2(SO4)2(H2O) and Hg3(Te3O8)(SO4). Notably, Hg3(Te3O8)(SO4) exhibits the largest birefringence at 532 nm (0.184) and 1064 nm (0.166) among the reported metal sulfate tellurites.

Graphical abstract: Hg3(Te3O8)(SO4): a new sulfate tellurite with a novel structure and large birefringence explored from d10 metal compounds

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Article information

DOI
https://doi.org/10.1039/D1CC02494A
Article type
Communication
Submitted
11 May 2021
Accepted
15 Jun 2021
First published
16 Jun 2021

Chem. Commun., 2021,57, 7039-7042

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Hg3(Te3O8)(SO4): a new sulfate tellurite with a novel structure and large birefringence explored from d10 metal compounds

P. Li, C. Hu, Y. Gong, F. Kong and J. Mao, Chem. Commun., 2021, 57, 7039 DOI: 10.1039/D1CC02494A

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