Nitrogen atom transfer mediated by a new PN3P-pincer nickel core via a putative nitrido nickel intermediate

Changguang Yao; Xiufang Wang; Kuo-Wei Huang

doi:10.1039/C7CC09804A

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Nitrogen atom transfer mediated by a new PN³P-pincer nickel core via a putative nitrido nickel intermediate†

Changguang Yao,^a Xiufang Wang^a and Kuo-Wei Huang

*^a

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* Corresponding authors

^a KAUST Catalysis Center and Division of Physical Sciences and Engineering, King Abdullah University of Science and Technology, Thuwal 23955-6900, Saudi Arabia
E-mail: hkw@kaust.edu.sa

Abstract

A 2nd generation PN³P-pincer azido nickel complex (PN³P)Ni(N₃) reacts with isocyanides to afford monosubstituted carbodiimides under irradiation, presumably via a transient nitrido intermediate. The resulting species can further generate unsymmetrical carboddimides and the PN³P nickel halide complex, accomplishing a synthetic cycle for a complete nitrogen atom transfer reaction.

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Article information

DOI: https://doi.org/10.1039/C7CC09804A
Article type: Communication
Submitted: 22 Dec 2017
Accepted: 13 Feb 2018
First published: 13 Feb 2018

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Chem. Commun., 2018,54, 3940-3943

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Nitrogen atom transfer mediated by a new PN³P-pincer nickel core via a putative nitrido nickel intermediate

C. Yao, X. Wang and K. Huang, Chem. Commun., 2018, 54, 3940 DOI: 10.1039/C7CC09804A

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