Craig
Sturgess
,
Christopher J.
Tuck
,
Ian A.
Ashcroft
and
Ricky D.
Wildman
*
Faculty of Engineering, Department of Mechanical, Materials and Manufacturing Engineering, University of Nottingham, Nottingham, NG7 2RD, UK. E-mail: Ricky.Wildman@Nottingham.ac.uk
First published on 21st August 2017
Material jetting is a process whereby liquid material can be deposited onto a substrate to solidify. Through a process of progressive additional layers, this deposition can then be used to produce 3D structures. However, the current material jetting catalogue is limited owing to the constraints on the viscosity of inks that can be deposited. Most inks currently being used are either solvent or photocuring based, with the latter becoming increasingly popular due to increased throughput. Full Reactive Inkjet Printing (FRIJP) is an alternative processing method currently being investigated as a route to widen the material catalogue. FRIJP is the combination, on the substrate, of two reactive components which then react together in contact on the substrate. In this work a two-part polydimethylsiloxane (PDMS) ink has been developed, printed individually, and cured. The successful printing of PDMS has been used to fabricate complex 3D geometry for the first time using FRIJP. Through the use of a prepared substrate feature resolutions up to 48 ± 2 μm (X, Y) were possible. Curing analysis has been conducted. It was found that not only does the reaction occur to a similar degree to conventional processes, but that there is no variation in the cured sample when printed at elevated substrate temperatures.
The extension of inkjet printing technology into 3D printing presents numerous challenges. Currently, the range of inkjet materials suitable for AM is limited. Previous research has focused on creating inks suitable for 2D deposition, where the layer thickness is unimportant and material loading can be low.9 For 3D Printing, the volumetric throughput is related to the layer thickness achievable given the functional loading of the ink. Initial approaches relied on loading solvents with nanoparticles10 or polymer,11–13 and evaporating the solvent to leave the desired solid. Newer approaches using photocurable14 and phase change materials15 offer substantially increased volumetric throughput in comparison, but are still limited in their material range. A further alternative is to combine reactive components to form the desired material during the manufacturing process itself.16 This fully reactive inkjet printing (FRIJP) inherits the advantages of inkjet printing, including sub-micron scale droplet positioning, sub-femtolitre volume control,17 and high processing speeds,7 whilst broadening the palette of materials available for additive manufacturing. Such a multi-component method has been demonstrated for the case of addition polymerisation to produce a polyurethane polymer,18 in the formation of nylon,19 and the reduction of metals, such as copper.20 Through this method, liquid droplets can be processed without chemical modification or external initiating steps.
Polydimethylsiloxane (PDMS) is a silicone elastomer that is widely used due to its low cost, biocompatibility, and optical transparency. One principle use of PDMS is the fabrication of microfluidic devices.21 The transparency of PDMS in visible light has led to developments in integrated optics;22 where optical waveguides have been fabricated that show mechanical compatibility with microfluidic channels and low attenuation losses.23–25 PDMS has also shown interesting properties when printing conductive tracks, for both adhesion of the ink and flexibility of the part.26 Recently, organosilicon self-assembled layers have been processed through reactive inkjet printing.27 However, despite these developments, a method for directly inkjet printing controlled PDMS structures has not been demonstrated.
Despite the lack of material jetting for PDMS fabrication, there has been some work with other additive manufacturing methods. Through the use of a supporting bath PDMS structures have been printed,28 after printing the bath medium acts a support for extended curing times and can be removed with a phosphate buffered saline solution. A multi-head extrusion system has demonstrated the printing of dyed premixed PDMS.29 The PDMS is extruded through a nozzle of 200 μm for use in vascular representations. The non-contact dispensing of premixed PDMS has been used for single droplet fabrication of lenses.30 Material jetting as a method has several advantages over material extrusion as discussed above, but the main ones are the ability to produce smaller features and a more scalable manufacturing method. An advantage specific to FRIJP is the ability to mix materials on the substrate, removing the need to mix reactive components before printing. The mixing on the substrate allows for faster curing components, able to fully cure at lower temperatures. These materials are then kept in a stable form inside the printing system. It also allows for the ability to vary the mixing ratio during printing, facilitating functional grading of parts.
In this paper a method for the multiple component reactive inkjet printing of PDMS structures is proposed. Two methods were considered. First, the reactants were deposited in complete layers, which led to the components, A and B, being printed with a separation of around two minutes. The second method used an improved strategy whereby both components were printed in a single pass. This reduced the delay between printing the PDMS components to around 0.3 s. The effect of the surface energy of the substrate on the wetting of the first layer of material was considered, as well as the development of a strategy for combining reactants and producing PDMS objects. Finally, the successful printing of an object and its subsequent characterisation will be used to demonstrate the approach as a method for 3D printing.
The advised operating range of the Dimatix Material Print head (DMP) (Dimatix, Fujifilm) employed for the printing is 10–12 mPa s and 28–33 mN m−1 for viscosity and surface tension respectively, but it is stated that viscosities as high as 30 mPa s and surface tensions up to 70 mN m−1 may be used.31 Two jettable inks were produced by creating 60 wt% solutions of PDMS A and B using octyl acetate (OA) as a viscosity modifier (Sigma Aldrich; O5500). This solvent was chosen as it was miscible with the PDMS formulations and offered a suitable vapour pressure for printing. The solutions were miscible and stable during formulation and printing. To further tune the viscosity, print head heating was used.
Ink viscosity was determined using a concentric cylinder rheometer (Malvern Kinexus Pro) with a shear rate sweep between 1 s−1 and 1000 s−1 and a temperature ramp between 20 °C and 70 °C. The ink formulation was judged to be printable when the viscosity was under the 30 mPa s threshold; further heating was found to achieve an ink viscosity below 20 mPa s at 60 °C. An important factor in inkjet printing, and also on how ink droplets form on the substrate, is the ink interfacial tension which was determined through the pendant drop method with a drop shape analyser (KRUSS DSA 100). It was found, however, that while the surface tension was inside the printable range, it was lower than the ideal range. The values for the viscosity and surface tension, for the PDMS components, solvent, and final inks are presented in Table 1.
Fluid | Viscosity (mPa s) 20 °C | Viscosity (mPa s) 60 °C | Interfacial tension (mN m−1) | Droplet mass (ng) |
---|---|---|---|---|
a Material MSDS. | ||||
PDMS A | 155a | 95.6 ± 0.6 | — | |
PDMS B | 200a | 74.8 ± 2.1 | — | |
Octyl acetate | 1.8533 | — | 27.833 | |
Ink A: OA (60% loading) | 38.2 ± 1.3 | 19.7 ± 0.25 | 23.6 ± 0.25 | 10.4 ± 0.24 |
Ink B: OA (60% loading) | 34.0 ± 0.1 | 17.7 ± 0.12 | 23.3 ± 0.13 | 11.92 ± 0.18 |
From the work of Reis32 it is understood that droplet volumes can be affected by a number of factors: ink viscosity, ink surface tension, and nozzle dimensions. This meant that despite the similar parameters associated with the A and B inks, differences were to be expected in droplet volume. This variation would then affect mixing ratio and the final curing. To accommodate this, firstly 100000 droplets were printed into a low weight metal pan and weighed, and then the obtained mass was used to change the droplet ratio during printing. Droplet masses were found to be 10.4 ng and 11.92 ng for ink A and B respectively.
To create the PFOTS-glass the pre-cleaned glass slides were first treated with 70% nitric acid (Sigma Aldrich 438073). They were then rinsed with anhydrous toluene (Sigma Aldrich 568821). After drying they were chemically coated with the PFOTS solution overnight. They were once again rinsed with anhydrous toluene before being baked in an oven at 100 °C for 1 hour.
The contact angle of the prepared PDMS ink was evaluated against the substrates using the sessile drop method with a drop shape analyser (KRUSS DSA 100). It was found that both the PTFE and PFOTS produced a higher contact angle than that of glass. A final substrate, of the cured PDMS was analysed which showed increased wetting over the PTFE and PFOTS. The results of the contact angle, shown in Table 2, suggest that the best feature resolution would be possible using the PFOTS substrate.
Raman spectral analysis was used to investigate the spatially varying cure, using a Horiba–Jobin–Yvon LabRAM Raman microscope (HORIBA, Japan), with an excitation laser wavelength of 532 nm and a 600 lines mm−1 grating. The detector was a Synapse CCD detector. The Raman shift was calibrated using a Si(100) reference sample. Scans were conducted in the print direction (Y), transverse to the print direction (X) and through the printed depth (Z). The complete scan dimensions were 750 μm × 750 μm × 100 μm (X, Y, and Z).
The FTIR-ATR was conducted on a Frontier (Perkin Elmer, USA) system. The ATR accessory was exclusively used for all sample analysis. Scans were initially conducted from 4000 to 650 cm−1, at a resolution of 4 cm−1. Later scans reduced the range to 2500 cm−1, thereby increasing the scan speed without losing information. The resulting spectra were taken from the average of four scans corrected by a baseline. The analysis was conducted in both Perkin Elmer's Spectrum software and using MATLAB to perform curve fitting for determination of the peak area.
Printing scheme | Analysis type | Analysis aim |
---|---|---|
Layer | Optical microscopy | Determine how the liquid pinning can be improved through the microstructuring method. |
Line | Optical microscopy | Determine the drop spacing suitable for FRIJP of PDMS using the line based method. |
Line and layer | Profile analysis | Determine distribution of material across the printed sample. |
Layer | Raman microscopy | To determine if there are concentration gradients in printed samples. |
Line | FTIR-ATR | To determine the degree of cure in the FRIJP method. |
The printed grids in Fig. 3 show that the cleaned glass produced the largest droplet size, which was greater than 150 μm. The PFOTS-glass and PTFE had similar spot sizes, at 48 ± 2 μm, and 64 ± 2 μm respectively. The smaller and more circular drops on the PFOTS-glass were likely due to the decreased surface roughness. The ability to clean the PFOTS-glass, and the increased hardness over the PTFE meant that it was the selected substrate for continued work.
To reduce the effect of uncontrolled liquid redistribution noted above, enhanced pinning between liquid–solid PDMS was investigated. The process used, termed microstructuring, involved the creation of pinning sites which act to increase the stability of any connected lines or films by creating an already established set of disconnected pinning sites. This method has been explored previously in regards to increasing solvent ink loading on a substrate.38Fig. 5 shows this process over a total of four reactive layers (eight printed layers). Initial spacing was set such that the first layer of the printed grid did not coalesce, only after the second layer of ink A was printed did coalescence occur. Once both components were printed the successive printing of layers resulted in a controlled coalescence. Finally, after four reactive layers the spreading was complete and complete coverage was achieved between the drops in the initially printed grid. This was accomplished with no undesired spreading outside the designated area.
Fig. 6 shows how this method is capable of producing continuous cured PDMS films with a high corner definition. Ultimately, the microstructuring method, along with substrate surface modification, allows for increased feature resolution and feature control.
The mechanism by which the microstructuring method works is similar to spin coating a substrate with a compatible polymer, but in this case the application of the microstructured pattern can afford greater control. This means it is possible to maintain the high feature resolution of the underlying substrate whilst increasing the pinning forces.
Once stable films were printed using the layer method, further layers were deposited to create thick films. In total 50 reactive layers, involving 50 layers of ink A and ink B, were deposited. The surface profiles of these films were then measured. The flatness of the top surface was of particular importance, since to build 3D structures, a known and repeatable layer thickness is required. It was expected that the long time to mixing would reduce flatness, but that the increased substrate temperature would mitigate this.
The results of the profile analysis are shown in Fig. 7. Differences in height profiles can be induced by altering the substrate temperature – for example, increasing the temperature from 40 °C to 60 °C shifts the profile from dome shaped, to one that is relatively flat. However, this uniformity is still subject to edge effects where material recedes from the outer edges. The layer height for these prints were; 12.1 ± 1.8 μm, 12.4 ± 1.4 μm, and 11.3 ± 1.9 μm for the sample printed at 40 °C, 60 °C, and 80 °C respectively. This height is calculated from the average and standard deviation of the heights across the total profile divided by the number of layers which was 50. This movement is known to be caused by the surface tension of the liquid, as discussed by Thompson.39 Further heating appears to maintain the same profile but increases the variation of material height throughout.
Fig. 8 Determination of the minimum drop spacing for stable line formation of printed PDMS. Ten layers of five lines were printed at different drop spacings. |
To understand the stability of the printed layers within the context of AM, the performance of multiple layers was then assessed. To maximise printing speed, the lowest droplet separation that achieved stable lines was chosen. The line stability was judged by the line morphology variation over many layers. For example, the 30 μm spacing showed continual spreading on each layer. From the results of the line stability tests a primary drop spacing of 40 μm was selected for future printing.
Substrate microscopy was used to characterise the printed films, and during the printing process after every layer an image was captured of the bottom left corner. Fig. 9 shows the growth of the PDMS sample during the first five layers. The first layer is directly printed onto the PFOTS-glass, and due to the fast curing rate it does not recede. Successive layers print onto the PDMS film and build up the layers to create the 3D object.
Fig. 9 FRIJP Line strategy printing directly onto the PFOTS-glass. The substrate temperature is 80 °C. |
As a demonstration of capability to print a fully 3D object in PDMS, a stepped ziggurat design was printed (Fig. 10). The design contained five steps, each printed with 30 reactive layers. Profile analysis shows the layer heights were less than those created with the layer printing strategy at; 8.3 ± 1.9 μm, 7.3 ± 1.4 μm, 6.3 ± 2.1 μm, 7.5 ± 1.5 μm, and 6.8 ± 1.5 μm for the first to last layer respectively. This reduced layer height is expected as the line based method used an increased drop spacing. In example, this increased spacing over a fixed 4 mm square area would result in 19000 drops printed for the line strategy, versus 26000 for the layer one.
Fig. 10 Stepped ziggurat, 4 × 4 mm PDMS consisting of 5 steps, each printed with 30 reactive layers. |
A consequence of the stepped ziggurat design was that it could be used to determine any effect of printed line length on the profile. For example, it can be seen in Fig. 11 in the Y (print) direction, increased scan length resulted in a more uniform layer height. The variation in this single sample is 17 μm for the first layer, increasing to 34 μm for the penultimate, shorter scan layer. The printing strategy in the layer based method is controlled so that each line printed takes the same amount of time, i.e. smaller printed patterns do not reduce the line scan time. Therefore, the only cause for this increased variation is due to a temperature gradient, where the sample on top is cooler than the bottom. The substrate was set to 80 °C and from previous results, reducing the substrate temperature led to increased variation.
The profile of the printed ziggurat, moving in the X direction across the stepped regions, shows that the first two steps produce a highly uniform and level line, but with further layers an inclination appears. This sloping is likely related to the increased variation in the other direction, indicative of increasing time to cure.
The process of FRIJP relies heavily on the ability of the two components to mix in situ, as there is little mixing from the drop impact.40 Therefore, in the case of FRIJP PDMS the sole mechanism for mixing is the diffusion of the two components. The miscibility of the inks aids this diffusion, and in the case of PDMS no effects from improper mixing were observed, e.g. interfaces, liquid PDMS, gelling. Confocal Raman was conducted to study if, and how, the substrate temperature can affect the mixing in RIJP. The analysis had two objectives. First it aimed to determine the residual crosslink component across the sample. Second, it set out to determine whether the PDMS is a homogenous polymer or if there are compositional variations.
For the analysis the residual hydride concentration is compared to the initial concentration. As mixing and reaction occurs this hydride will decrease, depending on the formulation once correctly mixed, there may or may not be excess hydride by design. To determine what the correct residual is, three calibration samples were also analysed with the Raman. The calibration samples were made following the manufacturers guide. In Fig. 12, the residual hydride component is compared to the initial concentration of Si–H in the PDMS A component (The representative spectra as shown in Supplementary 1, ESI†). This demonstrated that although there wasn’t exact correspondence, the printed samples tended to show similar PDMS A intensities to those seen in 1:1 cast samples, suggesting that printing results in material similar to that produced by more traditional manufacturing methods.
Fig. 12 Quantified residual crosslink component in each printed sample in relation to uncured part A also included are cast samples created at 1:1 2:1 3:1 A:B ratio, data is shown as mean ± standard deviation (XY: n = 75, Z: n = 50). Representative Raman spectra for the PDMS is shown in Supplementary 1 (ESI†). |
An important consideration of the FRIJP process is that due to transport in the film it is possible for the mixing ratio across the sample to change. Confocal Raman was used to determine if the ratio between A and B is constant throughout the printed sample. There was no evidence for spatial dependency in any of the samples printed (with the exception of the 40 °C X direction scan). In the case of samples prepared at the lower temperatures, scanned in the X direction, there is significance in the residual Si–H and location on the print. This residual concentration in the low temperature sample is likely related to the domed profile also observed. It was found that there is no evidence for depth dependent concentration, which has been found in AM inkjet printed components cured with UV radiation.41 This demonstration of mixing & reacting in situ suggests that it is possible to produce homogenously crosslinked PDMS samples. However, care must be taken that the individual components are deposited in the correct ratio and that limited redistribution of ink occurs before curing.
A further analysis was conducted on the samples printed using the second, line based, printing strategy. This printing strategy was also conducted with the corrected droplet ratios. The results of this analysis are shown in Fig. 13, they show that residual Si–H intensity in the printed samples corresponds to the 1:1 cast calibration. This shows that in all cases the printed samples were the same, or better, than the cast ones.
In FRIJP, as the reaction is separated into two inks, the time to cure not only includes the reaction, but also the time for deposition and mixing. To increase the control of the profile each one of these steps had to be shortened. The major concern was the time to mixing, which was dependent on the printed geometry, which was around 2 minutes (for 4 mm square sample) in the layer based approach. To reduce this both inks were printed in a single pass, the time to mixing was then independent of printed geometry and only dependent on head printing speed. The time to deposition was calculated to around 0.3 s. The reviewed literature stated no convective mixing occurred, leaving only diffusion based mixing for the PDMS system. The only method to increase this was then through substrate heating to elevate the liquid temperature.
Through the use of substrate heating it was found that the lowest degree of profile variation was found in the 80 °C print. This substrate heating also had an observable effect on the curing, with decreased residual Si–H components observed through Raman. When the line scan strategy was employed, to reduce the mixing time, substrate heating was maintained. The reduction on time to mixing had a direct effect on the printed profile, with the line scans showing much greater layer uniformity than the layer strategy. The sample curing was also improved with the change of strategy, where the samples showed residual Si–H component comparable to the conventionally manufactured 1:1 references.
The result of these improvements is a highly cross-linked PDMS network directly printed onto a glass substrate which was modified to increase the feature resolution. The printed geometry had an acceptable topology for a FRIJP part. A complex structure has been demonstrated, showing the capabilities of the FRIJP process to produce a single material sample without the aid of support. As it has been shown that PDMS samples can be produced through FRIJP the possibility to replace traditional casting techniques exists.
Footnote |
† Electronic supplementary information (ESI) available. See DOI: 10.1039/c7tc02412f |
This journal is © The Royal Society of Chemistry 2017 |