Non-isothermal kinetics of spin crossover

Mark B. Bushuev; Elena B. Nikolaenkova; Viktor P. Krivopalov

doi:10.1039/C7CP03442C

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Non-isothermal kinetics of spin crossover†

Mark B. Bushuev,

*^ab Elena B. Nikolaenkova^c and Viktor P. Krivopalov^c

Author affiliations

* Corresponding authors

^a Nikolaev Institute of Inorganic Chemistry, Siberian Branch of Russian Academy of Sciences, 3, Acad. Lavrentiev Ave., Novosibirsk, Russia
E-mail: bushuev@niic.nsc.ru, mark.bushuev@gmail.com
Fax: +7 383 330 94 89
Tel: +7 383 316 51 43

^b Novosibirsk State University, 2, Pirogova str., Novosibirsk, Russia

^c N. N. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch of Russian Academy of Sciences, 9, Acad. Lavrentiev Ave., Novosibirsk, Russia

Abstract

Non-isothermal magnetic studies can be used to estimate the activation energy of cooperative spin transition. Model-free isoconversional integral methods give reliable estimates of the activation barrier height for highly cooperative spin crossover systems with wide thermal hysteresis.

This article is part of the themed collection: 2017 PCCP HOT Articles

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Article information

DOI: https://doi.org/10.1039/C7CP03442C
Article type: Communication
Submitted: 22 May 2017
Accepted: 12 Jun 2017
First published: 12 Jun 2017

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Phys. Chem. Chem. Phys., 2017,19, 16955-16959

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Non-isothermal kinetics of spin crossover

M. B. Bushuev, E. B. Nikolaenkova and V. P. Krivopalov, Phys. Chem. Chem. Phys., 2017, 19, 16955 DOI: 10.1039/C7CP03442C

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Physical Chemistry Chemical Physics

Non-isothermal kinetics of spin crossover†

Abstract

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Non-isothermal kinetics of spin crossover

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