Issue 42, 2016

Water-dependent charge-transfer-induced spin transition of Prussian blue analogues

Abstract

Cobalt–iron Prussian blue analogues are magnetic functional compounds that exhibit charge-transfer-induced spin transition (CTIST), however, the role of guest species such as water in influencing the magnetic behaviour has remained unclear. Here, we report the water-dependent CTIST behaviour of Na0.46Co[Fe(CN)6]0.78(H2O)1.31 together with its single crystal X-ray structural analysis, for the first time.

Graphical abstract: Water-dependent charge-transfer-induced spin transition of Prussian blue analogues

Supplementary files

Article information

Article type
Communication
Submitted
06 Sep 2016
Accepted
29 Sep 2016
First published
30 Sep 2016

Dalton Trans., 2016,45, 16784-16788

Water-dependent charge-transfer-induced spin transition of Prussian blue analogues

H. Ohmagari, R. Ohtani, M. Nakaya, M. Ohba, M. Nakamura, L. F. Lindoy, O. Sato and S. Hayami, Dalton Trans., 2016, 45, 16784 DOI: 10.1039/C6DT03474H

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