Issue 41, 2015
From the journal:

Dalton Transactions

X-ray structure of a Ni(ii)–tri-phenoxyl radical complex†

Laurent Benisvy,*a   Galina M. Zats,a   Ohad Fleker,a   Dmitry S. Yufit,c   Maylis Orio,b   Galina Romanenkod  and  Victor Ovcharenkod  

* Corresponding authors

a Department of Chemistry, Bar-Ilan University, Ramat Gan 52900, Israel
E-mail: benisvy@gmail.com

b Aix Marseille Université, UMR 7313, Campus Scientifique de Saint-Jérôme, Avenue Escadrille Normandie-Niémen, 13397 Marseille Cedex 20, France

c Department of Chemistry, University of Durham, South Road, Durham DH1 3LE, UK

d International Tomography Center, SB RAS, 630090, Novosibirsk, Russia

Abstract

The diimino-diphenolato neutral square-planar Ni(II) complex, NiL2, is readily oxidised with 2 equiv. of Ag[SbF6], to produce an unprecedented octahedral Ni(II) tris(phenoxyl) radical complex, [Ni(L˙)3][SbF6]2. This study reveals, for the first time, the X-ray structure of a metal–tri-phenoxyl radical complex.

Graphical abstract: X-ray structure of a Ni(ii)–tri-phenoxyl radical complex

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C5DT03131A
Article type
Communication
Submitted
13 Aug 2015
Accepted
22 Sep 2015
First published
22 Sep 2015

Dalton Trans., 2015,44, 17924-17926

Author version available

Download author version (PDF)

Permissions

Request permissions

X-ray structure of a Ni(II)–tri-phenoxyl radical complex

L. Benisvy, G. M. Zats, O. Fleker, D. S. Yufit, M. Orio, G. Romanenko and V. Ovcharenko, Dalton Trans., 2015, 44, 17924 DOI: 10.1039/C5DT03131A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements