Issue 2, 2015
From the journal:

Dalton Transactions

In situ tetrazole templated chair-like decanuclear azido-cobalt(ii) SMM containing both tetra- and octa-hedral Co(ii) ions†

Yuan-Zhu Zhang,*ab   Song Gaoa  and  Osamu Sato*b  

* Corresponding authors

a Beijing National Laboratory for Molecular Sciences, State Key Laboratory of Rare Earth Materials Chemistry and Applications, College of Chemistry and Molecular Engineering, Peking University, 100871 Beijing, China
E-mail: yuanzhuzhang@gmail.com

b Institute for Materials Chemistry and Engineering, Kyushu University, 6-1 Kasuga, Fukuoka, Japan
E-mail: sato@cm.kyushu-u.ac.jp

Abstract

An azido-bridged chair-like decanuclear cluster: [CoII10(bzp)8(Metz)2(N3)18]·4MeOH·3H2O (1, bzp = 2-benzoylpyridine and HMetz = 5-methyl-1H-tetrazole) was prepared with in situ tetrazolate anions as templates in a sealed system. 1 containing both octahedral and tetrahedral Co(II) ions exhibited slow relaxation of magnetization with an effective barrier of 26 K under an applied dc field of 1 kOe.

Graphical abstract: In situ tetrazole templated chair-like decanuclear azido-cobalt(ii) SMM containing both tetra- and octa-hedral Co(ii) ions

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Article information

DOI
https://doi.org/10.1039/C4DT03211J
Article type
Communication
Submitted
17 Oct 2014
Accepted
05 Nov 2014
First published
10 Nov 2014

Dalton Trans., 2015,44, 480-483

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In situ tetrazole templated chair-like decanuclear azido-cobalt(II) SMM containing both tetra- and octa-hedral Co(II) ions

Y. Zhang, S. Gao and O. Sato, Dalton Trans., 2015, 44, 480 DOI: 10.1039/C4DT03211J

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