Happiness V.
Ijije
,
Richard C.
Lawrence
,
Nancy J.
Siambun†
,
Sang Mun
Jeong‡
,
Daniel A.
Jewell§
,
Di
Hu
and
George Z.
Chen
*
Department of Chemical and Environmental Engineering, and Energy and Sustainability Research Division, Faculty of Engineering, University of Nottingham, University Park, Nottingham NG7 2RD, UK. E-mail: george.chen@nottingham.ac.uk
First published on 7th May 2014
The electrochemical deposition and re-oxidation of solid carbon were studied in CO32− ion-containing molten salts (e.g. CaCl2–CaCO3–LiCl–KCl and Li2CO3–K2CO3) at temperatures between 500 and 800 °C under Ar, CO2 or N2–CO2 atmospheres. The electrode reactions were investigated by thermodynamic analysis, cyclic voltammetry and chronopotentiometry in a three-electrode cell under various conditions. The findings suggest that the electro-reduction of CO32− is dominated by carbon deposition on all three tested working electrodes (Ni, Pt and mild steel), but partial reduction to CO can also occur. Electro-re-oxidation of the deposited carbon in the same molten salts was investigated for potential applications in, for example, direct carbon fuel cells. A brief energy and cost analysis is given based on results from constant voltage electrolysis in a two-electrode cell.
The molten salt suitable for the electrolytic production of carbon from CO2 should be able to dissolve the O2− ion which is a product of carbon deposition, and also helps to absorb CO2 and convert it to the CO32− ion. Because of their low costs and environmental impacts, both chloride and carbonate salts, and in particular their mixtures, were investigated in this laboratory.8,11 It has been observed that electro-deposition of carbon can proceed in all tested molten salt combinations, as long as Li+ ions are present.1–4 In other cases, deposition is not impossible, but occurs at much lower rates.15 This phenomenon may be accounted for by the relative deposition potential of Li, Na, or K metal compared with that of carbon, as expressed by the following reactions:
2M2CO3 = 4M + 2CO2 + O2 (M = Li, Na or K) | (1) |
3M2CO3 = C + 3M2O + 2CO2 + O2 | (2) |
Note that reaction (2) is actually the sum of the following reactions (3) and (4) × 2:
M2CO3 = C + M2O + O2 | (3) |
M2CO3 = M2O + CO2 | (4) |
This combination aids electrochemical analysis, since both reactions (1) and (2) have the same anodic reaction (5) below:
2CO32− = 2CO2 + O2 + 4e (Eo = 0 V) | (5) |
The potentials of reactions (1) and (2) against reaction (5), i.e. a hypothetical reference electrode of CO32−/CO2–O2, are listed in Table 113 which shows that in molten alkali carbonates, carbon deposition is thermodynamically preferred to Li deposition, but more difficult than Na or K deposition, which is in line with experimental observations of the authors and others.1–4,15 (With reference to CO32−/CO2–O2, in the following discussion, the standard potential, Eo, provided next to the electrode reaction, is for the reaction occurring in pure molten Li2CO3 at 600 °C.)
Molten salt | Alkali metal | Carbon |
---|---|---|
Li2CO3 | −2.964 V | −1.719 V |
Na2CO3 | −2.546 V | −2.551 V |
K2CO3 | −2.612 V | −3.083 V |
CaCO3 | −3.033 V | −1.349 V |
BaCO3 | −3.069 V | −1.992 V |
Previous studies of the electro-deposition of carbon were mostly carried out in molten alkali metal salts. However, thermodynamic calculations show that it is also possible to use molten alkaline earth metal salts. It can be seen in Table 1 that carbon deposition is also preferred to alkaline earth metal deposition in both molten CaCO3 and BaCO3. However, CaCO3 decomposes at temperatures only slightly above its melting point (825 °C). MgCO3 is even worse and decomposes at temperatures below 350 °C before melting, which is the reason why Table 1 does not contain data for MgCO3. BaCO3 is thermally more stable but it is expensive to use, whilst barium salt toxicity is also a concern. Nevertheless, in this work, it was found that electro-deposition of carbon could be achieved in the molten mixture of CaCl2 and CaCO3 (84:
16 in a molar ratio) at temperatures higher than 730 °C. To lower the working temperature, mixtures of chlorides were used in some cases to dissolve CaCO3 and enable electro-deposition of carbon.
To enhance the carbon deposition, electrolysis was carried out in a two electrode cell under different CO2 partial pressures. The cathode was a mild steel rod of 5.0 mm dia., and the anode was a SnO2 rod of 10.0 mm dia. which functioned as an inert anode.16 A high cell voltage (4.0 V) was applied to gain a high deposition rate. The molten salt bath temperature was also increased to 579 °C for the same reason. The electrolysis current was observed to increase with the CO2 partial pressure as exemplified in Fig. 2a, in agreement with the reduction (6) and regeneration (7) of CO32− ions as follows:
CO32− + 4e = C + 3O2− (C1, Eo = −1.719 V) | (6) |
CO2 + O2− = CO32− | (7) |
Note that the bath compositions differ slightly in Fig. 1a and 2a, which was not intentional, but was due to the inconvenience of preparing the multicomponent molten salt bath. To compare the results, electrolysis was terminated at 1 h, and the cathode was removed from the bath. Fig. 2b displays a photograph of the cathodes, showing an increasing thickness of the deposited carbon coating with increasing CO2 partial pressure.
It is interesting to note in Fig. 2b that the surface of the deposited carbon was covered by small craters that were strong evidence of gas bubbles being formed on the cathode during electrolysis. This was thought to be CO formation via reaction (8). If not escaping from the molten salt, CO may undergo further changes on the electrode via reactions (9) and/or (10):
CO32− + 2e = CO + 2O2− (Eo = −0.947 V, A2) | (8) |
CO + 2e = C + O2− (Eo = −1.442 V, A1′) | (9) |
2CO + O2− = CO32− + C | (10) |
Note that (10) = (9) − (8), and it is a chemical reaction. However, the observed small craters in Fig. 2b seem to indicate slower kinetics of reactions (9) and (10), likely because CO was in the gas phase. Also, reactions (8) and (10) suggest that the O2− ions could prevent or reduce the formation of CO bubbles, which agrees with the absence of craters on the carbon coatings deposited from carbonate dominated baths, as discussed below.
The fairly symmetrical shape of peak C1 in Fig. 1a implies that Ni may have some catalytic effect on CO32− reduction. It was also observed that the current of the symmetrical peak C1 decreased significantly on the 2nd potential cycle, which may result from the Ni surface being covered by the deposited carbon and hence losing its catalytic effect. On the other hand, the absence of a re-oxidation counterpart of peak C1 suggests the irreversibility of the carbon deposition in the chloride dominated molten salt bath. This could be related to the CV being recorded under Ar, and that there were too few O2− and/or CO32− ions in the chloride dominated molten salt bath to assist carbon oxidation via reaction (11) or (12) below:6
C + 2O2− = CO2 + 4e (A1, Eo = −1.488 V) | (11) |
C + 2CO32− = 3CO2 + 4e (A3, Eo = −1.025 V) | (12) |
It was then thought that if the CVs were recorded in a carbonate dominated molten salt bath under CO2, carbon deposition and re-oxidation of the deposited carbon could both be facilitated. To confirm this, the molten eutectic mixture of Li2CO3–K2CO3 (molar ratio: 62:
38) was used to record CVs.11 Note that the Ni wire was replaced by a Pt wire which can offer a greater stability at more positive potentials to allow studies of all possible anodic reactions. Also, an alumina membrane Ag/AgCl reference electrode was used to offer a more stable reference potential.16
Typical CVs obtained in Li2CO3–K2CO3 are presented in Fig. 3. The potential window is about 1.90 V between the current onset potentials of peaks C1 (−1.65 V vs. Ag/AgCl) and A4 (0.25 V vs. Ag/AgCl) measured in Fig. 3a. This is slightly wider than that of pure Li2CO3 (1.72 V, Table 1), but it is understandable considering the influence of K2CO3. The CVs present a significant reduction peak C1, and several re-oxidation peaks as highlighted in Fig. 3b. To confirm that these anodic peaks are indeed due to re-oxidation of the deposited carbon, the potential was held at the cathodic limit (−2.0 V) for 10 s before the scan was reversed. In response, all anodic peaks increased significantly in current, whilst peak A1′ was engulfed in A1. This phenomenon can be explained as follows: more carbon was deposited when the potential was held at −2.0 V and hence contributed to greater re-oxidation currents. According to their relative potentials, peaks A1 and A3 can be attributed to reactions (11) and (12), respectively. Peaks A1′ and A2 were likely the reversals of reactions (9) and (8), respectively, considering their potentials relative to that of A1 for reaction (11). Interestingly, both peaks A2 and A3 shifted negatively after holding the potential scan at −2.0 V for 10 s. It is very likely that when CO is produced after peak A1′ via the reverse of reaction (9), it adsorbs on the carbon surface, impeding reaction (12) and hence there is a more positive potential for peak A3. Thus, the absence of A1′ on the CV after holding the potential at −2.0 V means a lowered influence of CO, and hence the negative shift of A3. If peak A2 corresponds to the reverse of reaction (8), its negative shift may result from a smaller number and size of the CO nuclei on the deposited carbon.
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Fig. 3 CVs of a Pt wire (0.25 mm dia.) in molten Li2CO3–K2CO3 (62![]() ![]() |
The oxidation current, A4, at the anodic potential limit (0.5 V) may be attributed to the discharge of either the O2− ion to form O2(13), or of the CO32− ion to form O2 and CO2(5).
2O2− = O2 + 4e (Eo = −0.463 V) | (13) |
If reaction (13) had occurred, its current should have appeared at potentials between A3 and A4 on the CV. However, for reaction (13) to proceed, a significant amount of O2− ions should be present near the electrode. This was unlikely to be the case, considering that the O2− ions, including those already present in the molten carbonate salts and those produced during carbon deposition via reaction (6), should have mostly been consumed in the course of the potential scan from A1 to A3. Thus, A4 should correspond to reaction (5).
Having obtained a basic understanding of the CV, further analysis was carried out to study the feasibility of employing the carbon deposition and dissolution processes for electrochemical energy storage and reuse. This effort started in this work by comparing the charges passed during the cathodic and anodic potential scans when recording the CVs. Some of the results obtained are listed in Table 2.
Scan rate (mV s−1) | Q − (C) | Q + (C) | Q +/Q− |
---|---|---|---|
a Note: all measurements were made using a fresh Pt working electrode in the same molten salt bath. | |||
100 | 3.575 | 1.776 | 0.50 |
80 | 6.220 | 3.151 | 0.51 |
60 | 6.524 | 3.362 | 0.52 |
40 | 10.75 | 5.737 | 0.53 |
20 | 25.56 | 14.41 | 0.56 |
10 | 73.56 | 47.70 | 0.65 |
As it can be seen in Table 2, the Q+/Q− ratio increased with a decreasing potential scan rate. In line with this trend, it was found that holding the potential for 10 s at the cathodic end could further increase the Q+/Q− ratio to close to 1. These observations imply that carbon deposition may not proceed well on the fresh Pt electrode, but becomes more efficient (although not necessarily quicker) after the Pt electrode is covered by the deposited carbon. In other words, carbon deposition on the Pt surface may proceed in competition with other reactions whose products do not remain on the electrode (e.g. CO formation), but these side reactions encounter higher kinetic barriers on the carbon surface. This understanding is practically important because it basically means that for the electro-deposition of carbon, the cathode material can be any metal or alloy as long as it is cathodically stable in the molten salt.
To further study the electro-oxidation of the deposited carbon, potentiostatic control was applied to produce a sufficient amount of carbon deposit for further analyses. In particular, chronopotentiometry was carried out to confirm reactions (11) and (12) as the main anodic reactions on the deposited carbon. In these experiments, the working electrode was a 5 mm dia. mild steel rod, whilst graphite, SnO2 and stainless steel were all tested as the counter electrode material, and similar results were obtained. However, stainless steel was proven to be the most convenient choice for various carbonate dominated baths, although minor anode dissolution and consequent contamination of the deposited carbon were observed.11 Thus, the following discussion will focus on data obtained from using the stainless steel counter electrode.
Fig. 4 compares the chronopotentiometric plots recorded during anodic oxidation (dissolution or galvanostatic discharge) of the electro-deposited carbon obtained under potentiostatic control. Both pure Li2CO3 and Li2CO3–K2CO3 were tested for comparison. On all plots in Fig. 4, there are two clearly distinguishable plateaux at potentials corresponding approximately to those of reactions (11) and (12). In Fig. 4b and c, a third potential plateau is shown at a more positive potential. The potential difference between the lowest and highest plateaux is about 1.75 V which can be explained by polarisations in addition to the theoretical value of 1.488 V between reactions (5) and (11). Polarisation is evident from a comparison between Fig. 4a and b. The potential difference between the first and second plateaux is about 0.40 V in Fig. 4a, but it increases to about 0.78 V in Fig. 4b. The larger current and lower temperature for recording Fig. 4b would have contributed to increasing both the ohmic and charge transfer polarisations. Thus, the third plateau can be attributed to reaction (5), i.e. electro-oxidation of the CO32− ion.
Similar to the CVs in Fig. 3 which indicate no clear presence of direct anodic discharge of the O2− ion, i.e. reaction (13), the plots in Fig. 4 also show only a barely visible inflexion of the rapidly increasing current between the 2nd and 3rd plateaux. This is understandable because the O2− activity must be significantly lower than that of the CO32− ion in the molten carbonate salts used. Also, these experiments were carried out under CO2 which could also help convert O2− to CO32−.
For energy storage, a high Q+/Q− ratio approaching 1 is desirable. Cyclic voltammetry has revealed promising results as shown in Table 2. More analyses were carried out on carbon coatings deposited under potentiostatic control and discharged (re-oxidised) via chronopotentiometry. Some of the preliminary findings are presented in Table 3.
E (V) | Q − (C) | I (mA) | Q +/Q−, 1st plateau | Q +/Q−, 2nd plateau |
---|---|---|---|---|
−1.68 | 1017 | 150 | 0.26 | 0.83 |
−1.68 | 973.6 | 300 | 0.17 | 0.48 |
−1.68 | 1301 | 450 | 0.18 | 0.34 |
−1.98 | 1764 | 300 | 0.16 | 0.32 |
−2.28 | 2318 | 300 | 0.15 | 0.28 |
The Q+/Q− ratio was found to be a complex function of both deposition and re-oxidation variables. The deposition potential (and voltage if in a two-electrode cell) plays the most significant role. With an increasingly negative deposition potential, the Q+/Q− ratio decreases quickly. This trend can be explained by parasitic reactions (e.g. CO formation) in competition with carbon deposition. Temperature change has a relatively small effect on the Q+/Q− ratio.
Increasing the deposition charge has a negative effect on the Q+/Q− ratio, whilst decreasing the re-oxidation current is beneficial. This can be related to the fact that the electro-deposited carbon is composed of various nanoparticulates, instead of a dense continuum.11 Thus, carbon loss from the electrode with a thick carbon coating is highly likely during electro-oxidation, particularly considering the disturbance from CO2 bubbles leaving the electrode at high re-oxidation currents.
It was observed in some cases that the overall Q+/Q− ratio would be higher if it were higher at the end of the first re-oxidation plateau (cf.Fig. 4 and Table 3). The first plateau corresponds to reaction (11) which produces one CO2 molecule at the expense of four electrons. At the second plateau, reaction (12) also involves four electrons, but creates three CO2 molecules. Thus, CO2 disturbance would be more significant at the second plateau than the first one, likely contributing to a greater non-electrochemical loss of carbon and hence a lower overall Q+/Q− ratio. Unfortunately, reaction (11) consumes O2− ions supplied to the electrode surface via diffusion which limits the maximum reaction rate. On the contrary, the CO32− ion in reaction (12) is a component of the molten carbonate salt and hence cannot be depleted at the electrode surface. Thus, to promote reaction (11) and mitigate the impact from CO2 disturbance during re-oxidation (discharge), a well-balanced engineering design of the bath composition and electrode and cell structures is crucial.
In addition to energy storage through electrochemical deposition and dissolution, the process of, and products from, indirect electro-reduction of CO2 to carbon can have other applications. For example, the deposited carbon can be used directly for making the electrodes of supercapacitors,10 or, after a proper treatment, for pollutant absorption. The process itself may be used to convert CO2 gas back to O2 gas, and hence support life in space, undersea, or in mines. It is thus worth making an estimation of the cost of the electro-deposition itself. In this work, a very high current efficiency (e.g. 95%) has been achieved in carbonate dominated baths. However, a voltage of or higher than 4.0 V was found to be necessary for electrolysis in the two-electrode cell,11 which is much higher than the thermodynamically predicted voltage as shown in Table 1. A possible reason is the relatively low activity of O2− ions in the carbonate dominated bath under CO2 that invokes reaction (5) instead of (13) as the anode reaction. Thus, it is reasonable to predict that the electrolysis voltage can be reduced to below 3.0 V if either Li2O or CaO is added to the molten salts. Nevertheless, even assuming a cell voltage of 3.0–4.0 V and a 95% current efficiency, the energy consumption of the electrolysis can be derived as 28.2–37.6 W h per kg-C, which can be translated to a cost of less than $5 per kg-C considering a 20% margin for heating and pre- and post-processing. For comparison, the current market price for supercapacitor grade activated carbon falls in the range of $20–40 per kg-C.
Footnotes |
† Current address: School of Engineering and Information Technology, Universiti Malaysia Sabah, 88999 Kota Kinabalu, Sabah, Malaysia. |
‡ Current address: Department of Chemical Engineering, Chungbuk National University, 410 Seongbongno, Heungduk-gu, Cheongju-si, Chungcheongbuk-do, 361-763, Republic of Korea. |
§ Current address: Coogee Titanium, Unit 4/25, Agosta Drive, Laverton North, VIC Australia 3026. |
This journal is © The Royal Society of Chemistry 2014 |