O.
Morawski
a,
A. L.
Sobolewski
a,
B.
Kozankiewicz
a,
L.
Sznitko
b and
A.
Miniewicz
*b
aInstitute of Physics, Polish Academy of Sciences, PL-02668 Warsaw, Poland
bInstitute of Physical and Theoretical Chemistry, Department of Chemistry, Wroclaw University of Technology, Wybrzeze Wyspianskiego 27, PL-50370 Wroclaw, Poland. E-mail: andrzej.miniewicz@pwr.edu.pl
First published on 29th October 2014
We study absorption and emission spectra of optically nonlinear single crystals of 3-(1,1-dicyanoethenyl)-1-phenyl-4,5-dihydro-1H-pyrazole (DCNP) at 5 K. We argue that fluorescence has a complex origin, it is emitted from the excitonic band, with the bottom at ∼18115 cm−1, and from trap states, and the two main traps have depths of ∼875 and ∼2465 cm−1. The excitonic origin of the emission is confirmed by the vibrational structure of fluorescence, closely resembling vibrations observed in the Raman scattering spectrum (recorded for DCNP crystals at 295 K) and by very short decay time of the excitonic emission, as a consequence of exciton migration and trapping at deep traps.
The title compound 3-(1,1-dicyanoethenyl)-1-phenyl-4,5-dihydro-1H-pyrazole, abbreviated as DCNP (C13H10N4, Mw = 222.25 g), is a good example of a low-molecular mass organic dye classified as a nonlinear optical chromophore due to its anisotropic “push–pull” character as described in ref. 12. The molecular structure of this compound has been schematically shown in Fig. 1. Fluorescence properties of the single crystals of DCNP under single and two-photon excitation conditions at temperatures between room and 77 K were already reported in ref. 14. Within this temperature range the fluorescence spectrum is composed of two broad bands, one centred at about 580 and the second at 640 nm, with continuous transfer of the intensity from the higher energy band to the lower energy band following a temperature increase. Such an observation raises the question about the origin of both bands. The present studies should also help in interpretation of luminescence from DCNP nanocrystals and amplified spontaneous emission and lasing.15
![]() | ||
Fig. 1 Projection of molecular packing in the crystal viewed along the b-axis (after ref. 13) and the molecular structure of DCNP (C13H10N4). |
DCNP crystallizes in the monoclinic non-centrosymmetric space group Cc (point group m) with pseudo-orthogonal geometry where Z = 4 molecules of DCNP occupy a unit cell. The first crystallographic structure of DCNP crystals was reported by Allen et al.12 The more precise structural studies of this compound both by X-ray and neutron diffraction have been done by Cole et al.13 at 90, 100, 200 and 290 K. The cell parameters a = 11.8751 Å, b = 12.3735 Å, c = 7.8876 Å, β = 90.412, and Z = 4 at 290 K have been measured by XRD.13 No phase transition was reported in this crystal down to 90 K. The densities at 290 K and 100 K as calculated from the unit cell parameters are 1.274 and 1.321 Mg m−3, respectively. The molecules are well aligned unidirectionally. From neutron diffraction studies13 it follows that the structure is stabilized by the presence of two weak intermolecular C–H⋯N hydrogen bonds. Parallel and head-to-tail arrangement of the molecules in the crystallographic structure, such that the nitrile group in one molecule is adjacent to the phenyl group in the next molecule, is directly responsible for the extremely large electro-optic coefficient of DCNP crystals, represented by the dominating second order susceptibility term χ(2)333(−ω;ω,0) = −2.3 × 10−9 m V−1,12 where the subscript 3 denotes the z-axis of the crystal that is nearly parallel to the long molecular axis.
Polarization of DCNP crystals at 290 K, calculated by considering four molecules with the ground state dipole moment μ = 7.5 D = 2.502 × 10−29 C m placed in a unit cell of the volume V = 1158.95 Å3 and oriented in the same direction, is equal to |P| = 0.116 C m−2. Recently, we confirmed that single crystals of DCNP indeed show a pyroelectric effect in the z-direction (unpublished results). Infrared (1064 nm) 5 ns pulses emitted by an Nd:YAG laser induced in a DCNP crystal an efficient fluorescence due to the two photon absorption process or the reabsorption of second order harmonic generation (SHG) light.14,15 Molecules of DCNP when dispersed in the polymer films of polyetherketone or PMMA, oriented by a high dc electric field, i.e. by a corona poling process, also show the efficient SHG phenomenon.16–18
The common property of the majority of molecular crystals, even those of the best quality, is the presence of trap states, which may be due to structural faults, vacancies, or chemical impurities. Particularly, for the DCNP we believe that the traps are of structural origin. The starting material was very carefully purified. Moreover, from the work of Black et al.19 it is known that for crystals grown from toluene solvent one deals with different growth rates along the polar axis of DCNP. Toluene appears to be selectively adsorbed at the faster growing polar end of the crystal (the cyano-rich direction) resulting in minor anisotropic misorientations being present in these crystals.19 This may point out that the main source of trapping states in DCNP single crystals is related to the presence of structural and not chemical traps.
Excitonic energy migration within the crystal, especially under ambient conditions, may result in efficient population of these trap states (as well as thermal depopulation of traps), therefore optical properties of a studied crystal may be disturbed by the traps. Thus, a deep understanding of the optical properties of a molecular crystal may require clarification of the origin of traps.
The first step into this direction is to determine trap's depths with respect to the crystal excitonic band. The purpose of the present work is to get experimental information about the energy location of the excitonic band in the single crystal of DCNP, which is necessary for determination of trap's depths. This goal is realized by studying absorption and fluorescence spectra of the crystal at 5 K. In order to convince ourselves that we are investigating the properties of the bulk crystal we compared the vibronic structure of fluorescence (recorded at 5 K) with Raman spectra (recorded at 295 K) of a DCNP crystal. We also analysed the vibronic structure of fluorescence and fluorescence excitation spectra of isolated DCNP molecules dispersed in a Shpol'skii matrix of n-nonane at 5 K. The spectral analysis is supported by the kinetic study.
This observation is a signature of the presence of small density of absorbing species whose transition dipole moment is parallel to the long axis of DCNP molecules, e.g. molecules or their clusters with reversed dipole moments with respect to the majority of molecules. Typical absorption coefficients for the molecular crystal above absorption edge are of the order of 103–104 cm−1. Our results (cf.Fig. 2) are consistent with the absorption spectrum recorded at room temperature by Allen et al.12 These authors observed a sharp absorption edge at 580 nm at room temperature, which is about 875 cm−1 lower in energy as compared with our absorption edge observed at 5 K. They also observed residual absorption at longer wavelengths, polarized (like in our study) along the long axis of DCNP molecules. “Red-shift” of the absorption edge between that measured at 5 K and at room temperature may be attributed to “hot absorption”, being the result of higher population of molecular vibrations in a crystal with a temperature increase. Another possible mechanism, acting in the same direction, is the change of the internal crystal energy with temperature: when temperature decreases the average crystal cohesive energy may increase, at the same time strengthening intermolecular interactions.
![]() | ||
Fig. 3 Fluorescence spectra of DCNP crystals at 5 K obtained with the excitation wavelengths of 560 and 581 nm, respectively. |
In the forthcoming presentation and discussion we concentrate on the excitonic emission (spread in the fluorescence spectrum between 552 and 575 nm). In order to confirm the excitonic origin of this emission we collected fluorescence at 5 K in two different detection configurations. We focused an excitation beam of the 445 nm light (excitation to the excitonic band) on the crystal surface to a spot of diameter of about 0.5 mm and collected emission light from this spot and next we shifted the detection spot 1 mm apart from the excitation spot. The results of such an experiment are presented in Fig. 4. It is clearly seen that the spectrum “off-spot” lacks the excitonic component and is composed of emission from trap states only.
In the “blue” part of the fluorescence spectrum, corresponding to the excitonic emission, fluorescence decays were found to be very fast, on the subnanosecond time scale. Fitting the decays to mono-exponential dependence by using deconvolution of the signal we found decay times equal to 210 ps for the observation at 555.5 nm and 255 ps at 564.8 nm, respectively. Considerably longer and non-exponential decays were detected at wavelengths of observation longer than 575 nm. Fitting the decay curves to bi-exponential dependence we got a short-lived component of about 1.3 ns and a long-lived component of about 5 ns. These two values were practically unchanged over the whole measured long wavelength spectral range of 570–700 nm, but with lengthening of the observation wavelength the amplitude of the long-lived component was raising whereas that of the short-lived one was decreasing. Kinetics of fluorescence emission observed at 640.1 nm shows a curve with maximum shifted in time with respect to the excitation pulse position; this is manifestation of the process of excitonic diffusion. Fluorescence decays shown in Fig. 5 point out to a complex excitation energy migration toward the trapping species. Traps strongly contribute to the emission of DCNP crystals at longer wavelengths. The most meaningful result is the very fast decay of excitonic fluorescence indicating efficient migration of excitons already at 5 K and their trapping at deep (at this temperature) trap states.
In order to confirm that the fluorescence spectrum detected within the 552–575 nm range has the excitonic (bulk) origin we compare the “blue” part of the spectrum presented already in Fig. 2 with the Raman spectrum of a single DCNP crystal (collected at 295 K). The result, where the spectra are compared and plotted in a wavenumber scale, is shown in Fig. 6a. Agreement between both spectra is quite good – several lines in the fluorescence spectrum have their partners in the Raman spectrum. A broad band, which builds up above 700 cm−1 (corresponding in Fig. 2 to wavelengths longer than 575 nm), is attributed to a deep trap state. Raman scattering reports on the molecular oscillation energies of the bulk crystal and is not sensitive to trap states (if the concentration of traps is low, like in DCNP crystals under study). The good matching of main Raman lines with the fluorescence fine structure clearly confirms the bulk origin of fluorescence emission in the considered spectral range (552–575 nm).
The vibrational structure of the Raman spectrum can be further used to get information about the origin of a deep trap contributing to the fluorescence spectrum of DCNP crystals at wavelengths longer than 580 nm. These traps, and deeper traps, are directly populated with the 582 nm excitation wavelength, as already shown in Fig. 3. Very good matching of both, Raman and fluorescence trap spectra is presented in Fig. 6b. This result convinced us that the trap as deep as ∼875 cm−1 below the excitonic band is also created on DCNP molecules, and not on chemical impurities. Fluorescence from impurities having different molecular structures than DCNP molecules should show fine structure different from that observed in the Raman scattering experiment.
Fluorescence decays for DCNP in a n-nonane matrix are mono-exponential and do not depend on the wavelength of observation as well as on temperature up to 180 K, above this temperature the n-nonane melts. The fluorescence decay time for the monomer is τmonomer = 4.8 ns, i.e. close to 3.7 and 5.6 ns, already reported for DCNP crystals at 293 K.14
Finally, let us mention that using a Parker type phosphorimeter, equipped with mechanical choppers and a sensitive EMCCD camera, we were not able to detect any long-lived (longer than 100 μs) phosphorescence emission in a DCNP crystal at 5 K. We scanned the whole spectral range between 600 and 1100 nm. Even more, our efforts to enhance intersystem crossing efficiency in DCNP by dissolving this compound in iodoethane, which is known to increase population of the triplet states due to the external heavy atom effect, appeared unsuccessful – we were not able to monitor any phosphorescence. We may thus conclude that intersystem crossing from the excited singlet state S1 to the triplet manifold in DCNP is not an efficient channel and excitation energy relaxation proceeds via radiative, fluorescence, and nonradiative, internal conversion channels.
Absorption spectra of the crystal were recorded in a single-beam configuration. In this case the light of a xenon lamp transmitted through the sample was dispersed using a McPherson 207 monochromator and detected using an EMI96659 photomultiplier operating in photon counting mode.
Fluorescence spectra were recorded at the right angle with respect to excitation, the emission light was dispersed using a McPherson 207 monochromator and detected either using an EMI96659 photomultiplier or using an EMCCD camera (Andor, model DU420A-BR-CD) cooled to 183 K. As an excitation source we used light emitted by either a cw 532 nm (10 mW) or 445 nm (20 mW) solid state lasers. Alternatively we used a Lambda Physics FL1001 dye laser pumped using a pulsed LPX100 excimer laser (λexc = 308 nm) which when operated with the Coumarin 102 dye was scanned within the spectral range between 470 and 500 nm and with Coumarin 153 between 530 and 605 nm, respectively. In the case of pulsed excitation, fluorescence signals were detected by the sampling technique using a photomultiplier and a Stanford Research SR259 boxcar averager.
The Raman scattering experiment was performed at 295 K using for excitation a cw Krypton laser operating at λR = 676.4 nm. The Raman spectrum was recorded using a Jobin Yvon T64000 spectrograph equipped with a CCD camera cooled by liquid nitrogen as a detector. The 676.4 nm light was weakly absorbed by a DCNP crystal, leading to weak fluorescence, and this fluorescence background was numerically subtracted from the detected Raman spectrum.
An important result of the work is to convince that the vibrational structure of the Raman spectrum (recorded under ambient conditions) can be successfully used to reproduce the vibrational structure of the fluorescence spectrum recorded at the cryogenic temperature (5 K). Good matching of the Raman spectrum and the fluorescence spectrum of the deep (at 5 K) trap (trap with the depth of ∼875 cm−1, and emission onset at 582 nm) argues that this trap is a kind of structural defect and does not correspond to a chemical impurity.
Finally, let us add that the present contribution is dedicated to the optical study of a DCNP crystal at 5 K. The optical studies of the crystal at elevated temperatures, where the deep traps play a dominant role and thus their origin is of main importance, will be considered in a forthcoming elaboration.
Footnote |
† Electronic supplementary information (ESI) is available: Spectra of DCNP in the n-nonane Shpol'skii matrix; Raman spectra of DCNP crystals; and table with calculated and measured frequencies of vibrations of DCNP molecules and in a crystal. See DOI: 10.1039/c4cp03634d |
This journal is © the Owner Societies 2014 |