Issue 10, 2014

Redox control of ferrocene-based complexes with systematically extended π-conjugated connectors: switchable and tailorable second order nonlinear optics

Abstract

The studies of geometrical structures, thermal stabilities, redox properties, nonlinear responses and optoelectronic properties have been carried out on a series of novel ferrocenyl (Fc) chromophores with the view of assessing their switchable and tailorable second order nonlinear optics (NLO). The use of a constant Fc donor and a 4,4′-bipyridinium acceptor and varied conjugated bridges makes it possible to systematically determine the contribution of organic connectors to chromophore nonlinear optical activities. The structures reveal that both the reduction reactions and organic connectors have a significant influence on 4,4′-bipyridinium. The potential energy surface maps along with plots of reduced density gradient mirror the thermal stabilities of the Fc-based chromophores. The first and second reductions take place preferentially at the 4,4′-bipyridinium moieties. Significantly, the reduction processes result in the molecular switches with large NLO contrast varying from zero or very small to a large value. Moreover, time-dependent density functional theory results indicate that the absorption peaks are mainly attributed to Fc to 4,4′-bipyridinium charge transfer and the mixture of intramolecular charge transfer within the two respective 4,4′-bipyridinium moieties coupled with interlayer charge transfer between the two 4,4′-bipyridinium moieties. This provides us with comprehensive information on the effect of organic connectors on the NLO properties.

Graphical abstract: Redox control of ferrocene-based complexes with systematically extended π-conjugated connectors: switchable and tailorable second order nonlinear optics

Supplementary files

Article information

Article type
Paper
Submitted
22 Oct 2013
Accepted
10 Jan 2014
First published
16 Jan 2014

Phys. Chem. Chem. Phys., 2014,16, 4900-4910

Redox control of ferrocene-based complexes with systematically extended π-conjugated connectors: switchable and tailorable second order nonlinear optics

W. Wang, N. Ma, S. Sun and Y. Qiu, Phys. Chem. Chem. Phys., 2014, 16, 4900 DOI: 10.1039/C3CP54468K

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