Issue 91, 2014

Bestowing structure upon the pores of a supramolecular network

Abstract

Trigonal molecules compartmentalise the pores of a honeycomb network of 3,4:9,10-tetracarboxylic diimide (PTCDI) and 1,3,5-triazine-2,4,6-triamine (melamine). Extending the 1,3,5-tri(phenylene-ethynylene)benzene core by a phenyl group allows for a well-defined accommodation of the molecule into two symmetry equivalent positions in the pore. The corresponding styryl or phenylene–ethynylene derivatives exceed the pore size and, thus, impede pore modification.

Graphical abstract: Bestowing structure upon the pores of a supramolecular network

Supplementary files

Article information

Article type
Communication
Submitted
30 Jul 2014
Accepted
19 Sep 2014
First published
03 Oct 2014

Chem. Commun., 2014,50, 14175-14178

Author version available

Bestowing structure upon the pores of a supramolecular network

B. Karamzadeh, T. Eaton, I. Cebula, D. M. Torres, M. Neuburger, M. Mayor and M. Buck, Chem. Commun., 2014, 50, 14175 DOI: 10.1039/C4CC05934D

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