Issue 61, 2014
From the journal:

Chemical Communications

The effect of π-conjugation in the macrocyclic ring on the photophysical properties of a series of thiaaceneporphyrinoids†

Young Mo Sung,a   Bartosz Szyszko,b   Radomir Myśliborski,b   Marcin Stępień,b   Juwon Oh,a   Minjung Son,a   Lechosław Latos-Grażyński*b  and  Dongho Kim*a  

* Corresponding authors

a Department of Chemistry, Yonsei University, Seoul 120-749, Korea
E-mail: dongho@yonsei.ac.kr
Fax: +82-2-2123-2434
Tel: +82-2-2123-2652

b Department of Chemistry, University of Wrocław, 14 F. Joliot-Curie street, Wrocław, Poland
E-mail: lechoslaw.latos-grazynski@chem.uni.wroc.pl
Fax: +48-713-282-348
Tel: +48-71-3757256

Abstract

In a series of thiaaceneporphyrinoids, their conformers exhibit macrocyclic π-conjugation pathways controlled by a dihedral angle between the porphyrin framework and acene planes. Conformational equilibria significantly affect the photophysical properties of these macrocycles.

Graphical abstract: The effect of π-conjugation in the macrocyclic ring on the photophysical properties of a series of thiaaceneporphyrinoids

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Article information

DOI
https://doi.org/10.1039/C4CC03855J
Article type
Communication
Submitted
20 May 2014
Accepted
10 Jun 2014
First published
10 Jun 2014

Chem. Commun., 2014,50, 8367-8369

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The effect of π-conjugation in the macrocyclic ring on the photophysical properties of a series of thiaaceneporphyrinoids

Y. M. Sung, B. Szyszko, R. Myśliborski, M. Stępień, J. Oh, M. Son, L. Latos-Grażyński and D. Kim, Chem. Commun., 2014, 50, 8367 DOI: 10.1039/C4CC03855J

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