Issue 63, 2014

Syntheses and electronic structures of μ-nitrido bridged pyridine, diimine iridium complexes

Abstract

The syntheses and X-ray crystal structures of dinuclear μ-azido and μ-nitrido bridged iridium complexes bearing the pyridine, diimine ligand (PDI) are reported. Their electronic structures and formal oxidation states of the metal centers are analyzed by theoretical and experimental methods, revealing the non-innocence of the PDI and nitrido ligands.

Graphical abstract: Syntheses and electronic structures of μ-nitrido bridged pyridine, diimine iridium complexes

Supplementary files

Article information

Article type
Communication
Submitted
14 May 2014
Accepted
06 Jun 2014
First published
09 Jun 2014

Chem. Commun., 2014,50, 8735-8738

Author version available

Syntheses and electronic structures of μ-nitrido bridged pyridine, diimine iridium complexes

F. Angersbach-Bludau, C. Schulz, J. Schöffel and P. Burger, Chem. Commun., 2014, 50, 8735 DOI: 10.1039/C4CC03624G

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements