Co-crystallized fullerene and a mixed (phthalocyaninato)(porphyrinato) dysprosium double-decker SMM†
Abstract
Effective and different inter-molecular interactions between fullerene C60 and tetrapyrrole-based double-decker single molecule magnets (SMMs) of three cocrystallates with different molar ratios rationalize the slight structural changes and different magnetic properties. The presented results indicate that different integration modes between the SMM and conjugated sp2-carbon substrate are able to affect the magnetic properties of the spintronic devices to different degrees, representing the effort towards understanding the effect of the conjugated sp2-carbon substrate on the magnetic properties of SMM spintronic devices at a molecular level.