Issue 45, 2013
From the journal:

Dalton Transactions

Cross-linked conjugated polymer assemblies at the air–water interface through supramoleculer bundling†

Rie Wakabayashi,a   Hiroshi Endo,b   Seiji Shinkai,cd   Katsuhiko Arigab  and  Masayuki Takeuchi*e  

* Corresponding authors

a Department of Applied Chemistry, Graduate School of Engineering, Kyushu University, 744 Motooka, Nishi-ku, Fukuoka 819-0395, Japan

b Supramolecules Group, World Premier International (WPI) Research Center for Materials Nanoarchitectonics (MANA), 1-1 Namiki, Tsukuba 305-0044, Japan

c Institute for Advanced Study, Kyushu University, Fukuoka 819-0395, Japan

d Institute of Systems, Information Technologies and Nanotechnologies (ISIT), Fukuoka 819-0385, Japan

e Organic Materials Group, National Institute for Materials Science (NIMS), 1-2-1 Sengen, Tsukuba 305-0047, Japan
E-mail: TAKEUCHI.Masayuki@nims.go,jp
Fax: +81 29 859 2101
Tel: +81 29 859 2110

Abstract

We demonstrated conjugated polymer assemblies formed by coordination interaction with a porphyrinatozinc cross-linker at the air–water interface by means of the Langmuir–Blodgett technique. The coordination bonds were maintained at the interface, though the spacing between the polymer backbones in the Langmuir film was smaller than that in bulk solution, probably because of the influence of the interface. The successful transfer of the films to a substrate enabled the fabrication of a large-scale conjugated polymer material.

Graphical abstract: Cross-linked conjugated polymer assemblies at the air–water interface through supramoleculer bundling

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Article information

DOI
https://doi.org/10.1039/C3DT51468D
Article type
Communication
Submitted
03 Jun 2013
Accepted
07 Aug 2013
First published
20 Aug 2013

Dalton Trans., 2013,42, 15911-15914

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Cross-linked conjugated polymer assemblies at the air–water interface through supramoleculer bundling

R. Wakabayashi, H. Endo, S. Shinkai, K. Ariga and M. Takeuchi, Dalton Trans., 2013, 42, 15911 DOI: 10.1039/C3DT51468D

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