Vibrational dynamics of acetate in D2O studied by infrared pump–probe spectroscopy

Abstract

Solute–solvent interactions between acetate and D₂O were investigated by vibrational spectroscopic methods. The vibrational dynamics of the COO asymmetric stretching mode in D₂O was observed by time-resolved infrared (IR) pump–probe spectroscopy. The pump–probe signal contained both decay and oscillatory components. The time dependence of the decay component could be explained by a double exponential function with time constants of 200 fs and 2.6 ps, which are the same for both the COO asymmetric and symmetric stretching modes. The Fourier spectrum of the oscillatory component contained a band around 80 cm⁻¹, which suggests that the COO asymmetric stretching mode couples to a low-frequency vibrational mode with a wavenumber of 80 cm⁻¹. Based on quantum chemistry calculations, we propose that a bridged complex comprising an acetate ion and one D₂O molecule, in which the two oxygen atoms in the acetate anion form hydrogen bonds with the two deuterium atoms in D₂O, is the most stable structure. The 80 cm⁻¹ low-frequency mode was assigned to the asymmetric stretching vibration of the hydrogen bond in the bridged complex.