Issue 9, 2012
From the journal:

Chemical Communications

Suzuki–Miyaura cross-couplings of secondary allylic boronic esters†‡

Ben W. Glasspoole,a   Kazem Ghozati,a   Jonathon W. Moira  and  Cathleen M. Crudden*a  

* Corresponding authors

a Department of Chemistry, Queen's University, 90 Bader Lane, Kingston, ON, K7L 6N3 Canada
E-mail: cruddenc@chem.queensu.ca
Fax: (613) 533-6669
Tel: (613)533-6000 x36755

Abstract

Palladium-catalyzed cross-coupling reactions of secondary allylic boronic esters with iodoarenes were demonstrated under the conditions previously described for the coupling of benzylic substrates. The regioselectivity of the process was largely dictated by the pattern of olefin substitution.

Graphical abstract: Suzuki–Miyaura cross-couplings of secondary allylic boronic esters

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Article information

DOI
https://doi.org/10.1039/C2CC16076E
Article type
Communication
Submitted
29 Sep 2011
Accepted
25 Nov 2011
First published
19 Dec 2011

Chem. Commun., 2012,48, 1230-1232

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Suzuki–Miyaura cross-couplings of secondary allylic boronic esters

B. W. Glasspoole, K. Ghozati, J. W. Moir and C. M. Crudden, Chem. Commun., 2012, 48, 1230 DOI: 10.1039/C2CC16076E

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