Issue 6, 2012
From the journal:

Chemical Communications

Cationic terminal hydrido rare earth complexes bearing an amidinate ancillary ligand†

Jianhua Chenga  and  Zhaomin Hou*a  

* Corresponding authors

a Organometallic Chemistry Laboratory and Advanced Catalyst Research Team, RIKEN Advanced Science Institute, 2-1 Hirosawa, Wako, Saitama 351-0198, Japan
E-mail: houz@riken.jp
Fax: +81 48-462-4665

Abstract

The first well defined cationic terminal hydrido rare earth complexes [(NCN)LnH(THF)3][BPh4] were isolated from THF, which on recrystallization from chlorobenzene gave reversibly the novel dicationic binuclear dihydride complexes [(NCN)Ln(μ-H)(THF)2]2[BPh4]2.

Graphical abstract: Cationic terminal hydrido rare earth complexes bearing an amidinate ancillary ligand

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Article information

DOI
https://doi.org/10.1039/C1CC14949K
Article type
Communication
Submitted
10 Aug 2011
Accepted
03 Oct 2011
First published
20 Oct 2011

Chem. Commun., 2012,48, 814-816

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Cationic terminal hydrido rare earth complexes bearing an amidinate ancillary ligand

J. Cheng and Z. Hou, Chem. Commun., 2012, 48, 814 DOI: 10.1039/C1CC14949K

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