Issue 45, 2011
From the journal:

Chemical Communications

Isolation of a stable lacunary Dawson-type polyoxomolybdate cluster†

Akihiro Hashikawa,a   Makiko Fujimoto,a   Yoshihito Hayashi*a  and  Hitoshi Miyasakaa  

* Corresponding authors

a Department of Chemistry, Kanazawa University, Kakuma, Kanazawa 920-1192, Japan
E-mail: hayashi@se.kanazawa-u.ac.jp
Fax: +81 76-264-5742
Tel: +81 76-264-5695

Abstract

A polyoxotetradecamolybdate cluster [Mo14O38(OAc)6]2−, which has a lacunary core of the Wells–Dawson structure, is isolated by the reduction of [Mo6O19]2−. The Mo14 core is comprised of a mixed valence of [MoV4MoVI10], exhibiting multi-step reversible redox processes that experience both oxidation and reduction.

Graphical abstract: Isolation of a stable lacunary Dawson-type polyoxomolybdate cluster

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Article information

DOI
https://doi.org/10.1039/C1CC15439G
Article type
Communication
Submitted
01 Sep 2011
Accepted
06 Oct 2011
First published
20 Oct 2011

Chem. Commun., 2011,47, 12361-12363

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Isolation of a stable lacunary Dawson-type polyoxomolybdate cluster

A. Hashikawa, M. Fujimoto, Y. Hayashi and H. Miyasaka, Chem. Commun., 2011, 47, 12361 DOI: 10.1039/C1CC15439G

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