Issue 42, 2011
From the journal:

Chemical Communications

An oxidative cross-dehydrogenative-coupling reaction in water using molecular oxygen as the oxidant: vanadium catalyzed indolation of tetrahydroisoquinolines†

Kaliyamoorthy Alagiri,a   Guralamatta Siddappa Ravi Kumaraa  and  Kandikere Ramaiah Prabhu*a  

* Corresponding authors

a Department of Organic Chemistry, Indian Institute of Science, Bangalore 560 012, Karnataka, India
E-mail: prabhu@orgchem.iisc.ernet.in
Fax: +91-80-23600529

Abstract

An aerobic oxidative cross-dehydrogenative coupling reaction between sp3 C–H and sp2 C–H bonds is developed by employing a vanadium catalyst (10 mol%) in an aqueous medium using molecular oxygen as the oxidant. This environmentally benign strategy exhibits larger substrate scope and shows high regioselectivity.

Graphical abstract: An oxidative cross-dehydrogenative-coupling reaction in water using molecular oxygen as the oxidant: vanadium catalyzed indolation of tetrahydroisoquinolines

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Article information

DOI
https://doi.org/10.1039/C1CC15050B
Article type
Communication
Submitted
14 Aug 2011
Accepted
12 Sep 2011
First published
28 Sep 2011

Chem. Commun., 2011,47, 11787-11789

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An oxidative cross-dehydrogenative-coupling reaction in water using molecular oxygen as the oxidant: vanadium catalyzed indolation of tetrahydroisoquinolines

K. Alagiri, G. S. R. Kumara and K. R. Prabhu, Chem. Commun., 2011, 47, 11787 DOI: 10.1039/C1CC15050B

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