Issue 17, 2010
From the journal:

Chemical Communications

Transition metal-catalyzed addition reactions of arylboronic acids with alkyl 2-formylbenzoates: efficient access to chiral 3-substituted phthalides†‡

Chun-Hui Xing,a   Yuan-Xi Liao,a   Ping Hea  and  Qiao-Sheng Hu*a  

* Corresponding authors

a Department of Chemistry, College of Staten Island and the Graduate Center of the City University of New York, 2800 Victory Boulevard, Staten Island, New York 10314, USA
E-mail: qiaosheng.hu@csi.cuny.edu
Fax: (+1) 718-982-3910
Tel: (+1) 718-982-3901

Abstract

Transition metal-catalyzed addition of arylboronic acids to 2-formylbenzoates afforded 3-substituted phthalides. By using SPINOL-based phosphites as ligands, a Rh(I)-catalyzed asymmetric version of such an addition reaction was achieved.

Graphical abstract: Transition metal-catalyzed addition reactions of arylboronic acids with alkyl 2-formylbenzoates: efficient access to chiral 3-substituted phthalides

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Article information

DOI
https://doi.org/10.1039/C001104E
Article type
Communication
Submitted
18 Jan 2010
Accepted
18 Feb 2010
First published
25 Mar 2010

Chem. Commun., 2010,46, 3010-3012

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Transition metal-catalyzed addition reactions of arylboronic acids with alkyl 2-formylbenzoates: efficient access to chiral 3-substituted phthalides

C. Xing, Y. Liao, P. He and Q. Hu, Chem. Commun., 2010, 46, 3010 DOI: 10.1039/C001104E

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