Issue 20, 2010
From the journal:

Chemical Communications

Heterobimetallic porphyrin-based single-chain magnet constructed from manganese(iii)-porphyrin and trans-dicyanobis(acetylacetonato) ruthenate(iii) containing co-crystallized bulk anions and cations†

Daopeng Zhang,a   Li-Fang Zhang,a   Yuting Chen,a   Hailong Wang,a   Zhong-Hai Ni,*a   Wolfgang Wernsdorferc  and  Jianzhuang Jiang*ab  

* Corresponding authors

a Department of Chemistry, Shandong University, Jinan 250100, China
E-mail: jzjiang@sdu.edu.cn, nizhh@sdu.edu.cn

b Departmentof Chemistry, University of Science and Technology Beijing, Beijing 100083, China

c Laboratoire Louis Néel-CNRS, 38042 Grenoble Cedex 9, France

Abstract

Two cyanide-bridged alternated 1 : 1 RuIII/MnIII complexes structurally characterized as single-chain containing co-crystallized bulk anions and cations have been successfully assembled from [Mn(TPP)(H2O)2]+ and [Ru(acac)2(CN)2]− blocks. Systematic investigation of their magnetic properties reveals typical single-chain magnet (SCM) behaviors for both of them.

Graphical abstract: Heterobimetallic porphyrin-based single-chain magnet constructed from manganese(iii)-porphyrin and trans-dicyanobis(acetylacetonato) ruthenate(iii) containing co-crystallized bulk anions and cations

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Article information

DOI
https://doi.org/10.1039/B926710G
Article type
Communication
Submitted
17 Dec 2009
Accepted
17 Feb 2010
First published
24 Mar 2010

Chem. Commun., 2010,46, 3550-3552

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Heterobimetallic porphyrin-based single-chain magnet constructed from manganese(III)-porphyrin and trans-dicyanobis(acetylacetonato) ruthenate(III) containing co-crystallized bulk anions and cations

D. Zhang, L. Zhang, Y. Chen, H. Wang, Z. Ni, W. Wernsdorfer and J. Jiang, Chem. Commun., 2010, 46, 3550 DOI: 10.1039/B926710G

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