Issue 40, 2009
From the journal:

Chemical Communications

Non-catalytic conversion of C–F bonds of benzotrifluorides to C–C bonds using organoaluminium reagents†

Jun Terao,*a   Misaki Nakamurab  and  Nobuaki Kambe*b  

* Corresponding authors

a Department of Energy and Hydrocarbon Chemistry, Graduate School of Engineering, Kyoto University, Japan
E-mail: terao@scl.kyoto-u.ac.jp
Fax: +81 75-383-2516
Tel: +81 75-383-2514

b Department of Applied Chemistry Graduate School of Engineering, Osaka University, Yamadaoka 2-1, Suita, Japan
E-mail: kambe@chem.eng.osaka-u.ac.jp
Fax: +81 6-6879-7390
Tel: +81 6-6879-7388

Abstract

A facile method for the conversion of C–F bonds of benzotrifluorides to C–C bonds has been developed using aluminium reagents in the absence of catalysts.

Graphical abstract: Non-catalytic conversion of C–F bonds of benzotrifluorides to C–C bonds using organoaluminium reagents

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Article information

DOI
https://doi.org/10.1039/B915620H
Article type
Communication
Submitted
30 Jul 2009
Accepted
10 Sep 2009
First published
22 Sep 2009

Chem. Commun., 2009, 6011-6013

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Non-catalytic conversion of C–F bonds of benzotrifluorides to C–C bonds using organoaluminium reagents

J. Terao, M. Nakamura and N. Kambe, Chem. Commun., 2009, 6011 DOI: 10.1039/B915620H

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