Issue 12, 2008
From the journal:

CrystEngComm

Solvent as structure directing agent for the synthesis of novel coordination frameworks using a tripodal flexible ligand†

Sujit K. Ghosha  and  Susumu Kitagawa*abc  

* Corresponding authors

a Department of Synthetic Chemistry and Biological Chemistry, Kyoto University, Katsura, Nishikyo-ku, Kyoto, Japan
E-mail: kitagawa@sbchem.kyoto-u.ac.jp

b Kitagawa Integrated Pore Project, ERATO, JST, Kyoto Research Park, Bldg#3, Shimogyo-ku, Kyoto, Japan

c Institute for Integrated Cell-Material Sciences (iCeMS), Kyoto University, 69 Konoe-cho, Yoshida, Sokyo-ku, Kyoto, Japan

Abstract

Three novel three-dimensional (3D) coordination polymers have been synthesized by the self-assembly of a flexible tricarboxylate ligand and Cd(II) metal ion in dimethylformamide (DMF), diethylformamide (DEF) and isopropanol (PrOH), where changes of solvent with different size and shape lead to the formation of solvent templated neutral and anionic frameworks with different pore sizes and shapes as shown by X-ray crystallography.

Graphical abstract: Solvent as structure directing agent for the synthesis of novel coordination frameworks using a tripodal flexible ligand

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Article information

DOI
https://doi.org/10.1039/B812645C
Article type
Communication
Submitted
23 Jul 2008
Accepted
24 Sep 2008
First published
15 Oct 2008

CrystEngComm, 2008,10, 1739-1742

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Solvent as structure directing agent for the synthesis of novel coordination frameworks using a tripodal flexible ligand

S. K. Ghosh and S. Kitagawa, CrystEngComm, 2008, 10, 1739 DOI: 10.1039/B812645C

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