Issue 4, 2007
From the journal:

Chemical Communications

Increased crystal porosity and enhanced gas adsorption by intracolumnar gliding for broadband gas detection

Panče Naumov,*ab   Kenji Sakurai,c   Akihiko Nukuia  and  Masahiko Tanakad  

* Corresponding authors

a ICYS, National Institute for Materials Science, 1-1 Namiki, Tsukuba, Ibaraki, Japan
E-mail: naumov.pance@nims.go.jp
Fax: +81-29-860-4706
Tel: +81-29-851-3354 8572

b Institute of Chemistry, Faculty of Science, Sts. Cyril and Methodius University, POB 162, Skopje, Macedonia

c X-ray Physics Laboratory, Quantum Beam Center, National Institute for Materials Science, 1-2-1 Sengen, Tsukuba, Ibaraki, Japan

d WEBRAM, SPring-8, National Institute for Materials Science, 1-1-1 Kouto, Mikazuki-cho, Sayo-gun, Hyogo, Japan

Abstract

A new three-level structural approach based on anion-induced intracolumnar gliding of stacked coordinatively unsaturated units is described for design of metal–organic crystals which exhibit concentration- and gas-specific adsorption of a variety of small molecules and could be employed for multiple and rapid qualitative and quantitative broadband detection of gases or gaseous mixtures.

Graphical abstract: Increased crystal porosity and enhanced gas adsorption by intracolumnar gliding for broadband gas detection

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Article information

DOI
https://doi.org/10.1039/B610950K
Article type
Communication
Submitted
31 Jul 2006
Accepted
24 Oct 2006
First published
14 Nov 2006

Chem. Commun., 2007, 347-349

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Increased crystal porosity and enhanced gas adsorption by intracolumnar gliding for broadband gas detection

P. Naumov, K. Sakurai, A. Nukui and M. Tanaka, Chem. Commun., 2007, 347 DOI: 10.1039/B610950K

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