Issue 22, 2004
From the journal:

Chemical Communications

An unprecedented intramolecular coupling of o-carboranyl and cyclopentadienyl. Synthesis and structural characterization of a ruthenium complex containing a novel doubly-bridged cyclopentadienyl-carboranyl ligand†

Yi Sun,a   Hoi-Shan Chan,a   Pierre H. Dixneufb  and  Zuowei Xie*a  

* Corresponding authors

a Department of Chemistry, The Chinese University of Hong Kong, Shatin, Hong Kong, China

b Institut de Chimie de Rennes, UMR 6509 CNRS, Université de Rennes, Organométalliques et Catalyse, Campus de Beaulieu, 35042 Rennes, France

Abstract

A novel ruthenium-mediated coupling reaction of a carboranyl with a cyclopentadienyl was discovered for the first time, leading to a brand new doubly-bridged cyclopentadienyl-carboranyl ligand bearing two five-membered rings and to a new type of chiral ruthenium complex.

Graphical abstract: An unprecedented intramolecular coupling of o-carboranyl and cyclopentadienyl. Synthesis and structural characterization of a ruthenium complex containing a novel doubly-bridged cyclopentadienyl-carboranyl ligand

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Article information

DOI
https://doi.org/10.1039/B409772F
Article type
Communication
Submitted
28 Jun 2004
Accepted
04 Aug 2004
First published
30 Sep 2004

Chem. Commun., 2004, 2588-2589

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An unprecedented intramolecular coupling of o-carboranyl and cyclopentadienyl. Synthesis and structural characterization of a ruthenium complex containing a novel doubly-bridged cyclopentadienyl-carboranyl ligand

Y. Sun, H. Chan, P. H. Dixneuf and Z. Xie, Chem. Commun., 2004, 2588 DOI: 10.1039/B409772F

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