Issue 19, 2004
From the journal:

Chemical Communications

A modular ditopic crown-shielded phosphate ion-pair receptor†

Patrick Gunning,a   Andrew C. Benniston*b  and  Robert D. Peacock*a  

* Corresponding authors

a Department of Chemistry, Joseph Black Building, University of Glasgow, Glasgow, UK
E-mail: bob@chem.gla.ac.uk
Fax: +44 (0)141 330 4888
Tel: +44 (0)141 330 4375

b Molecular Photonics Laboratory, University of Newcastle, Newcastle upon Tyne, UK
E-mail: a.c.benniston@ncl.ac.uk
Fax: +44 (0)191 222 6929
Tel: +44 (0)191 222 5706

Abstract

The synthesis of a modular hybrid receptor containing both an aza macrocycle and crown ether is described; a complete thermodynamic characterisation of the binding properties, in water, of the zinc(II) complex of the receptor towards phosphate is presented and the parameters are compared to those of the aza macrocycle precursor.

Graphical abstract: A modular ditopic crown-shielded phosphate ion-pair receptor

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Article information

DOI
https://doi.org/10.1039/B409132A
Article type
Communication
Submitted
17 Jun 2004
Accepted
16 Jul 2004
First published
20 Aug 2004

Chem. Commun., 2004, 2226-2227

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A modular ditopic crown-shielded phosphate ion-pair receptor

P. Gunning, A. C. Benniston and R. D. Peacock, Chem. Commun., 2004, 2226 DOI: 10.1039/B409132A

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