Novel hybrid hetero-sandwich architectures via stoichiometric control of host–guest self-organization

Zhi Yu; Kui Yu; Longli Lai; Kostantin A. Udachin; Haoguo Zhu; Jianqin Tao; Xiaozeng You; Markus Ströbele; H.-Jürgen Meyer; John A. Ripmeester

doi:10.1039/B313846A

Novel hybrid hetero-sandwich architectures via stoichiometric control of host–guest self-organization†

Zhi Yu,*^ab Kui Yu,^a Longli Lai,‡^a Kostantin A. Udachin,^a Haoguo Zhu,^b Jianqin Tao,^b Xiaozeng You,^b Markus Ströbele,^c H.-Jürgen Meyer^c and John A. Ripmeester*^a

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* Corresponding authors

^a Steacie Institute for Molecular Sciences of National Research Council Canada, 100 Sussex Drive, Ottawa, Ontario K1A 0R6, Canada
E-mail: John.Ripmeester@nrc-cnrc.gc.ca

^b State Key Laboratory of Coordination Chemistry, Coordination Chemistry Institute, Nanjing University, Nanjing, 210093, China
E-mail: zhiyu@netra.nju.edu.cn

^c Institut für Anorganische Chemie, Tübingen University, D-72076, Tübingen, Germany

Abstract

Thiocyanate cadmium and methylviologen hybrid host–guest compounds give two novel multiple sandwich architectures with regular or irregular grids of the anionic layer in the structures as effected by the molar ratios of starting ingredients, and show evidence of charge-transfer to the organic dications.

Chemical Communications

Novel hybrid hetero-sandwich architectures via stoichiometric control of host–guest self-organization†

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Novel hybrid hetero-sandwich architectures via stoichiometric control of host–guest self-organization

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