Formation of carbon nanocapsules with SiC nanoparticles prepared by polymer pyrolysis

(Note: The full text of this document is currently only available in the PDF Version )

Takeo Oku, Koichi Niihara and Katsuaki Suganuma


Abstract

Carbon nanocapsules with SiC nanoparticles were produced by thermal decomposition of polyvinyl alcohol with SiC clusters at 500 °C in Ar gas atmosphere. High-resolution electron microscopy also showed the formation of carbon hollow structures such as nanoparticles, polyhedra, and clusters. The present work indicates that the pyrolysis of polymer materials with clusters is a useful fabrication method for the mass-production of carbon nanocapsules at low temperatures compared to the ordinary arc discharge method.


References

  1. H. W. Kroto, J. R. Heath, S. C. O'Brien and R. E. Smalley, Nature (London), 1985, 318, 162 CrossRef CAS.
  2. S. Iijima, Nature (London), 1991, 354, 56 CrossRef CAS.
  3. D. Ugarte, Nature (London), 1992, 359, 707 CrossRef CAS.
  4. Y. Saito, T. Yoshikawa, M. Inagaki, M. Tomita and T. Hayashi, Chem. Phys. Lett., 1993, 204, 277 CrossRef CAS.
  5. A. Krishnan, E. Dujardin, M. M. J. Treacy, J. Hugdahl, S. Lynum and T. W. Ebbesen, Nature (London), 1997, 388, 451 CrossRef CAS.
  6. Y. Saito, T. Yoshikawa, M. Okuda, N. Fujimoto, K. Sumiyama, K. Suzuki, A. Kasuya and Y. Nisina, J. Phys. Chem. Solids, 1993, 54, 1849 CrossRef CAS.
  7. J. Sloan, J. Cook, M. L. H. Green, J. L. Hutchinson and R. Tenne, J. Mater. Chem., 1997, 7, 1089 RSC.
  8. L. Rapoport, Y. Bilik, Y. Feldman, M. Homyonfer, S. R. Cohen and R. Tenne, Nature (London), 1997, 387, 791 CrossRef CAS.
  9. Kuraray Co., Ltd., Osaka, Japan.
  10. B. R. Elliott, J. J. Host, V. P. Dravid, M. H. Teng and J.-H. Hwang, J. Mater. Res., 1997, 12, 3328 CAS.
  11. W. Krätschmer, L. D. Lamb, K. Fostiropoulos and D. R. Huffman, Nature (London), 1990, 347, 354 CrossRef.
  12. K. Suganuma, G. Sasaki, T. Fujita, M. Okumura and K. Niihara, J. Mater. Sci., 1993, 28, 1175 CAS.
  13. C. M. Wang, M. Mitomo and H. Emoto, J. Mater. Res., 1997, 12, 3266 CAS.
  14. M. Kusunoki, M. Rokkaku and T. Suzuki, Appl. Phys. Lett., 1997, 71, 2620 CrossRef CAS.
  15. P. J. F. Harris and S. C. Tsang, Philos. Mag. A, 1997, 76, 667 Search PubMed.