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DOI: 10.1039/A803212B (Paper) Reference Section for: Chem. Commun., 1998, 1429-1430

A highly coupled RuIII–RuII system incorporating sulfur donor ligands

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Sue Roche, Jim A. Thomas and Lesley J. Yellowlees

Abstract

Bimetallic complex 1, which is based on a RuII metal centre incorporating sulfur donor ligands, shows strong intermetallic coupling in its mixed valence state comparable to those observed in complexes incorporating conventional nitrogen donors.

References

  1. See, for example: (a) J. Poppe, M. Moscherosch and W. Kaim, Inorg. Chem., 1993, 32, 1640; (b) J. E. B. Johnson, C. DeGroff and R. R. Ruminski, Inorg. Chim. Acta, 1991, 187, 73 CrossRef CAS; (c) D. E. Richardson and H. Taube, Coord. Chem. Rev., 1984, 60, 107 CrossRef CAS.
  2. C. Creutz and H. Taube, J. Am. Chem. Soc., 1969, 91, 3988 CrossRef CAS; 1973, 95, 1086.
  3. (a) J. R. Miller, Electron transfer in Inorganic, Organic, and Biological systems, ch. 17, ed. J. R. Bolton, N. Mataga and G. McLendon, Advances in Chemistry Series, 228, American Chemical Society, Washington, DC, 1991 Search PubMed; (b) N. S. Hush, Prog. Inorg. Chem., 1967, 8, 391 CAS; (c) C. Creutz, Prog. Inorg. Chem., 1983, 30, 1 CAS; (d) R. J. Crutchley, Adv. Inorg. Chem., 1994, 41, 273 CAS.
  4. M. D. Ward, Chem. Ind. (London), 1996, 568 CAS; 1997, 640.
  5. V. Balzani and F. Scandola, Pure Appl. Chem., 1990, 8, 1457.
  6. W. Kaim, V. Kasack, H. Binder, E. Roth and J. Jordanov, Angew. Chem., Int. Ed. Engl., 1988, 27, 1174 CrossRef; M. Haga, T. Ano, K. Kano and S. Yamabe, Inorg. Chem., 1991, 30, 3843 CrossRef CAS; J.-P. Collin, R. Laine, J.-P. Launay, J.-P. Sauvage and A. Sour, J. Chem. Soc., Chem. Commun., 1994, 434 Search PubMed; M. A. S. Aquino, F. L. Lee, E. J. Gabe, C. Bensimon, J. E. Greedau and R. J. Crutchley, J. Am. Chem. Soc., 1992, 114, 5130 CrossRef CAS.
  7. E. M. Kober, K. A. Goldsby, D. N. S. Narayana and T. J. Meyer, J. Am. Chem. Soc., 1983, 105, 4303 CrossRef CAS; S. Ernst, V. Kasack and W. Kaim, Inorg. Chem., 1988, 27, 1146 CrossRef CAS; S. Ernst and W. Kaim, Inorg. Chem., 1989, 28, 1520 CrossRef CAS; W. Kaim and S. Kohlmann, Inorg. Chem., 1990, 29, 2909 CrossRef CAS.
  8. C. Landgrafe and W. S. Sheldrick, J. Chem. Soc., Dalton Trans., 1994, 1885 RSC.
  9. E. S. Lewis and M. D. Johnson, J. Am. Chem. Soc., 1959, 81, 2070 CrossRef CAS.
  10. G. E. D. Mullen, M. J. Went, S. Wocadlo, A. K. Powell and P. J. Blower, Angew. Chem., Int. Ed. Engl., 1997, 36, 1205 CrossRef CAS.
  11. S. Kohlmann, S. Ernst and W. Kaim, Angew. Chem., Int. Ed. Engl., 1985, 24, 8684 CrossRef.
  12. M. B. Robin and P. Day, Adv. Inorg. Chem. Radiochem., 1967, 10, 247 Search PubMed.
  13. H. S. Lim, J. Barclay and F. C. Anson, Inorg. Chem., 1972, 11, 1460 CrossRef CAS.