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DOI: 10.1039/A707910I (Paper) Reference Section for: Chem. Commun., 1998, 569-570

Model investigations for vanadium–protein interactions: first vanadium(III) complexes with dipeptides and their oxovanadium(IV) analogues

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Anastasios J. Tasiopoulos, Themistoklis A. Kabanos, Yiannis G. Deligiannakis, J. Derek Woollins, J. Derek Woollins and Alexandra M. Z. Slawin

Abstract

Reaction of the dipeptides H2Gly-Tyr and H2Gly-Phe with VCl3 and 1,10-phenanthroline affords the compounds [V(Gly-Tyr)(phen)]Cl·3MeOH 1 and [V(Gly-Phe)(phen)]Cl·3MeOH 2; aerial oxidation of the complexes 1 and 2 gives their oxovanadium(IV) analogues [VO(Gly-Tyr)(phen)] 3 and [VO(Gly-Phe(phen)] 4, respectively; the X-ray crystal structure of 3 is reported.

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