Synthesis and electrochemistry of a tetrathiafulvalene (TTF)21–glycol dendrimer: intradendrimer aggregation of TTF cation radicals

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Christian A. Christensen, Jan Becher, Christian A. Christensen, Leonid M. Goldenberg and Martin R. Bryce


Abstract

The convergent synthesis of a TTF–glycol dendrimer is reported: thin layer cyclic voltammetric studies on (TTF)21 system 11 show that all the TTF units undergo two single-electron oxidations to produce the 42+ redox state spectroelectrochemical studies establish that there are intradendrimer interactions between partially-oxidised TTF units.


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