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DOI: 10.1039/A607182A (Paper) Reference Section for: J. Chem. Soc., Dalton Trans., 1997, 701-706

Co-ordination complexes as organic–inorganic layer magnets

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Peter Day

Abstract

Examples are given of transition-metal co-ordination complexes that give rise to alternating layers of organic and inorganic moieties in the solid state exhibiting finite zero-field magnetisation at low temperature. The mechanisms of magnetic exchange included are ferromagnetism, ferrimagnetism and canted antiferromagnetism.

References

  1. L. Pauling, The Nature of the Chemical Bond, Cornell University Press, Ithaca, 1948 Search PubMed.
  2. See, for example, B. N. Figgis and J. Lewis, in Modern Coordination Chemistry, eds. J. Lewis and R. G. Wilkins, Interscience, New York, 1960, ch. 6 Search PubMed.
  3. See, for example, J. B. Goodenough, Magnetism and the Chemical Bond, Interscience, New York, 1963 Search PubMed.
  4. A. Ginsberg, Inorg. Chim. Acta Rev., 1971, 5, 45 Search PubMed.
  5. P. Day, A. K. Gregson, D. H. Leech and M. J. Fair, J. Chem. Soc., Dalton Trans., 1975, 1306 RSC.
  6. P. Day, J. Magn. Magn. Mater., 1986, 54 and 57, 1442 CrossRef.
  7. P. Day, Acc. Chem. Res., 1979, 12, 236 CrossRef CAS.
  8. C. Bellitto and P. Day, J. Mater. Chem., 1992, 2, 265 RSC.
  9. P. Day, Chem. Soc. Rev., 1993, 22, 51 RSC.
  10. C. Bellitto, M. J. Fair, T. E. Wood and P. Day, J. Chem. Soc., Faraday Trans. 2, 1980, 1579 Search PubMed.
  11. P. J. Fyne, P. Day, M. T. Hutchings, S. Depinna, B. C. Cavenett and R. Pynn, J. Phys. C., 1984, 17, L245 CrossRef CAS.
  12. P. Day, Philos. Trans. R. Soc. London, Ser. A, 1985, 314, 145 Search PubMed.
  13. See, for example, R. L. Carlin, Magnetochemistry, Springer, Berlin, 1986, p. 30 Search PubMed.
  14. T. Moriya, Phys. Rev., 1960, 117, 635 CrossRef CAS; 12091.
  15. S. G. Carling, P. Day and D. Visser, J. Solid State Chem., 1993, 106, 111 CrossRef CAS.
  16. S. G. Carling, P. Day and D. Visser, Inorg. Chem., 1995, 34, 3917 CrossRef CAS.
  17. H. Arend, W. Haber, F. H. Mischgvorsky and G. K. Richter-van Leeuwen, J. Cryst. Growth, 1978, 42, 213 CrossRef.
  18. S. G. Carling, P. Day and D. Visser, Solid State Commun., 1992, 88, 135 CrossRef.
  19. S. G. Carling, P. Day and D. Visser, J. Phys.: Condens. Matter, 1995, 7, L109 CrossRef CAS.
  20. S. T. Bramwell and P. C. W. Holdsworth, J. Phys.: Condens. Matter, 1992, 5, L53 CrossRef.
  21. H. I. Tamaki, Z. J. Zhong, N. Matsumoto, S. Kida, M. Koikawa, N. Achiwa, Y. Hashimoto and H. Okawa, J. Am. Chem. Soc., 1992, 114, 6974 CrossRef.
  22. S. G. Carling, C. Mathoniere, P. Day, K. M. A. Malik, S. J. Coles and M. B. Hursthouse, J. Chem. Soc., Dalton Trans., 1996, 1839 RSC.
  23. C. Mathoniere, C. J. Nuttall, S. G. Carling and P. Day, Inorg. Chem., 1996, 35, 1201 CrossRef CAS.
  24. S. Descurtins, H. W. Schmalle, H. R. Oswald, A. Linden, J. Enslig, P. Gütlich and A. Hauser, Inorg. Chim. Acta, 1994, 216, 65 CrossRef CAS.
  25. L. O. Atovmyan, G. V. Shilov, R. N. Lyubovskaya, E. I. Zhilyaeva, N. S. Ovanesyan, S. I. Piramova and I. G. Gusakovskaya, JETP Lett., 1993, 58, 766.
  26. M. Julve, J. Faus, M. Verdaguer and A. Gleizes, J. Am. Chem. Soc., 1984, 106, 8306 CrossRef CAS.
  27. C. Mathoniere, S. G. Carling, Y. Dou and P. Day, J. Chem. Soc., Chem. Commun., 1994, 1551 RSC.
  28. J. B. Goodenough, Magnetism and the Chemical Bond, Interscience, New York, 1963 Search PubMed.
  29. L. Néel, Ann. Phys., 1948, 1, 137.
  30. P. Day, in Magnetism: a Supramolecular Function, ed. O. Kahn, Kluwer, Dordrecht, 1996, p. 467 Search PubMed.