View PDF Version
 
DOI: 10.1039/A608202E (Paper) Reference Section for: Chem. Commun., 1997, 583-584

Metal selection of ligand functionality in [(mes)2P([horiz bar, double dot above]O)2Li·2thf]2 and [{(Me3Si)2N}Cd{(mes)2P [horiz bar, double dot above]O}2Li·2thf] (mes = C6H2Me3-2,4,6)

(Note: The full text of this document is currently only available in the PDF Version )

Michael A. Beswick, Natalie L. Cromhout, Christopher N. Harmer, Julie S. Palmer, Paul R. Raithby, Alexander Steiner, Kerry L. Verhorevoort and Dominic S. Wright

Abstract

The reaction of LiBun with [(mes)2P(H)[double bond, length as m-dash]O] affords the diorganophosphinate complex [(mes)2P([horiz bar, double dot above]O)2Li·2thf] 1 and [(mes)2PLi], however, addition of [Cd{N(SiMe3)2}2] to the mixture gives the diorganophosphinite complex [{Me3- Si)2N}Cd{(mes)2P[horiz bar, double dot above]O}2 Li·2thf] 2; the formation of these complexes illustrates that the ligand functionality of 1 can be controlled by the character of the coordinated metal ion.

References

  1. For examples, see: (a) P. Colamarino, P. L. Orioli, W. D. Benzinger and H. D. Gillman, Inorg. Chem., 1976, 15, 800 CrossRef CAS ; (b) H.-H. Detjen, E. Lindner and J. Strahle, Chem. Ber., 1978, 111, 2067 ; (c) A.-F. Shihada and F. Weller, Z. Anorg. Allg. Chem., 1981, 472, 102 CrossRef CAS ; (d) K. W. Oliver, S. J. Rettig, R. C. Thomas and J. Trotter, Can. J. Chem., 1982, 60, 2017 CAS ; (e) R. Cini, P. Orioli, M. Sabat and H. D. Gillman, Inorg. Chim. Acta, 1982, 59, 225 CrossRef CAS ; (f) S. Blosl, W. Schwarz and A. Schmidt, Z. Naturforsch., Teil B, 1983, 38, 143 Search PubMed ; (g) J. Haynes, K. W. Oliver, S. J. Rettig, R. C. Thomson and J. Trotter, Can. J. Chem., 1984, 62, 891 CAS ; (h) R. O. Day, J. M. Holmes, V. Chaudrasekhar and R. R. Holmes, J. Am. Chem. Soc., 1987, 109, 940 CrossRef CAS ; (i) R. R. Holmes, K. C. K. Swamy, C. G. Schmid and R. O. Day, J. Am. Chem. Soc., 1988, 110, 7060 CrossRef CAS ; (j) P. Betz and A. Bino, Inorg. Chim. Acta, 1988, 147, 109 CrossRef CAS ; (k) R. O. Day, V. Chadrasekhar, K. C. K. Swamy, J. M. Holmes, S. D. Burton and R. R. Holmes, Inorg. Chem., 1988, 27, 2887 CrossRef CAS ; (l) A. M. Arif and A. R. Barron, Polyhedron, 1988, 7, 2091 CrossRef CAS ; (m) F. E. Hahn, B. Schneider and F.-W. Reier, Z. Naturforsch., Teil B, 1990, 45, 134 CAS ; (n) K. C. K. Swamy, R. O. Day and R. R. Holmes, Inorg. Chem., 1992, 31, 4184 CrossRef CAS ; (o) P. Leoni, F. Marchett and M. Pasquali, J. Organomet. Chem., 1993, 451, C25 CrossRef CAS .
  2. Homonuclear examples, see: G. Munding, B. Schilling, M. Weishaupt, E. Lindner and J. Strahle, Z. Anorg. Allg. Chem., 1977, 437, 169 Search PubMed ; S. Hoehne, E. Lindner and B. Schilling, J. Organomet. Chem., 1977, 139, 315 CrossRef CAS ; D. E. Berry, K. A. Beveridge, J. Browning, G. W. Bushnell and K. K. Dixon, Can. J. Chem., 1986, 64, 1903 CrossRef CAS ; D. E. Fogg, N. J. Taylor, A. Meyer and A. J. Carty, Organometallics, 1987, 6, 2252 CAS ; N. W. Alcock, P. Bergamini, T. M. Gomes-Carniero, R. D. Jackson, J. Nicholls, A. G. Orpen, P. G. Pringle, S. Sostero and O. Traverso, J. Chem. Soc., Chem. Commun., 1990, 980 CrossRef CAS ; H. Brunner, R. Eder, B. Hammer and U. Klement, J. Organomet. Chem., 1990, 394, 555 RSC ; I. J. B. Lin, T. S. Lai, Ling-Kang Liu and Y. S. Wen, J. Organomet. Chem., 1990, 399, 361 CrossRef CAS ; D. Matt, F. Ingold, F. Balegronne and D. Grandjean, J. Organomet. Chem., 1990, 339, 349 CrossRef CAS ; R. O. Day, P. R. Holmes, A. Schmidpeter, K. Stoll and L. Howe, Chem. Ber., 1991, 124, 2443 CrossRef CAS ; A. Beguin, H.-C. Bottcher, M. C. Dai, G. Rheingold, H. Stoeckli-Evans, G. Suss-Fink and B. Watther, Chimia, 1993, 47, 192 CrossRef CAS ; U. Florke and H.-J. Haupte, Z. Kristallogr., 1993, 205, 119 CAS ; V. Riera, M. A. Ruiz, F. Willafane, C. Bois and Y. Jeannin, Organometallics, 1993, 12, 124 .
  3. Heteronuclear examples, see: J. R. Allen, G. H. W. Milburn, L. Sawyer and V. K. Shah, Acta Crystallogr., Sect. C, 1985, 41, 58 Search PubMed ; J. R. Allen, J. Halfpenny, G. H. W. Milburn and P. M. Veitch, J. Chem. Res., 1986, 279, 2601 CrossRef ; P. M. Veitch, J. R. Allen, A. J. Blake and M. Schroder, J. Chem. Soc., Dalton Trans., 1987, 2853 Search PubMed ; D. M. Anderson, A. J. Blake, J. D. Fotheringham, T. A. Stephenson, J. R. Allen and P. M. Veitch, Acta. Crystallogr., Sect. C, 1988, 44, 1305 RSC ; U. Kolle, G. Flunkert, R. Gorissen, M. U. Schmidt and U. Englert, Angew. Chem., Int. Ed. Engl., 1992, 31, 440 CrossRef .
  4. (a) Methoden der Organischen Chemie(Houben-Weyl), Phosphor-Verbindungen I, Georg Theime Verlag, Stuttgart, 1982, vol. E1, p. 242 Search PubMed ; (b) H.-J. Kleiner, Liebig Ann. Chem., 1974, 751 Search PubMed ; (c) Fabw. Hoeschst., Erif: H.-J. Kleiner and K. Schimmelshmidt, Chem. Abstr., 74 88129K, 1971 Search PubMed .
  5. Lithium Chemistry—A Theoretical and Experimental Overview, ed. A.-M. Sapse and P. von Rague Schleyer, Wiley, New York, 1995, ch. 9 and references therein Search PubMed .
  6. There are only a few structurally characterised cadmium diorganophosphide complexes (containing R2P–Cd), see M. A. Matchett, M. Y. Chiang and W. E. Burho, Inorg. Chem., 1994, 33, 1109 Search PubMed ; S. C. Goel, M. Y. Chiang, D. J. Rauscher and W. E. Burho, J. Am. Chem. Soc., 1993, 115, 160 CrossRef CAS ; B. L. Benac, A. H. Cowley, R. A. Jones, C. M. Nunn and T. C. Wright, J. Am. Chem. Soc., 1989, 111, 4986 CrossRef CAS ; A. Eichöfer, J. Eisenmann, D. Fenske and F. Simon, Z. Anorg. Allg. Chem., 1993, 691, 1360 CrossRef CAS .
  7. E. Lindner and G. Frey, Chem. Ber., 1980, 113, 2769; 3261 .
  8. T. Kottke and D. Stalke, J. Appl. Crystallogr., 1993, 26, 615 CrossRef .
  9. G. M. Sheldrick, SHELXL-93, Göttingen, 1993 .
Click here to see how this site uses Cookies. View our privacy policy here.