A chiral ferrocenylboronic acid 1 bearing an intramolecular tertiary amine binds saccharides at ca. pH 7, the complexation event, which can be conveniently detected by an electrochemical method, shows chiral discrimination for certain linear saccharides.
A. Ori and S. Shinkai, J. Chem. Soc., Chem. Commun., 1995, 1771 DOI: 10.1039/C39950001771
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