Formation of carbonyl ylides from the reaction of keto α-diazoacetates with rhodium (II) acetate has been found to be dependent on the electrophilicity of the intermediate rhodium carbenoid.
D. C. Dean, K. E. Krumpe and A. Padwa, J. Chem. Soc., Chem. Commun., 1989, 921 DOI: 10.1039/C39890000921
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