Issue 4, 1984

Large stereoelectronic effect in 1,3-dehydrohalogenation to form a 1,3-dipole

Abstract

The E-hydroximidoyl chloride (5), prepared on photoisomerisation of (1) to (2) and by subsequent hydrolysis, is shown to lose HCl to give benzonitrile oxide 6 × 107 fold slower than the Z-isomer (3).

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1984, 229-230

Large stereoelectronic effect in 1,3-dehydrohalogenation to form a 1,3-dipole

A. F. Hegarty and M. Mullane, J. Chem. Soc., Chem. Commun., 1984, 229 DOI: 10.1039/C39840000229

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