Under flash vacuum pyrolysis, dioxabicyclo[n.2.1]alkanes (n= 3,4, and 5) isomerise to keto-aldehydes, MeCO[CH2]nCHO, whereas dioxabicyclo[n.2.2]alkanes (n= 2,3, and 4) fragment ot give, by loss of hydrogen and ethylene, mixtures of cycloalkane-1,4-diones and dialdehydes, OHC[CH2]nCHO.
A. J. Broodworth, D. S. Baker and H. J. Eggelte, J. Chem. Soc., Chem. Commun., 1982, 1034 DOI: 10.1039/C39820001034
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