In contrast with their oxo-analogues, thioenamides undergo photochemical cyclization to yield isoquinolinethione derivatives which are easily converted into isoquinolones and tetrahydroisoquinolines by treatment with benzeneseleninic anhydride and EtO3BF4–NaBH4, respectively.
A. Couture, R. Dubiez and A. Lableche-Combier, J. Chem. Soc., Chem. Commun., 1982, 842 DOI: 10.1039/C39820000842
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