In the presence of certain rhodium(I) complexes, anthraquinone was found to react with amines to give the 1-alkylaminoanthraquinones, along with small amounts of the 1,4-bis(alkylamino)anthraquinones; this direct amination characteristically occurs only at the α-position of anthraquinone.
K. Mita, T. Yamagishi and M. Hida, J. Chem. Soc., Chem. Commun., 1980, 1036 DOI: 10.1039/C39800001036
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